Characterization of residual-resistance-ratio of Cu stabilizer in commercial REBCO tapes

IF 1.8 3区 工程技术 Q3 PHYSICS, APPLIED Cryogenics Pub Date : 2024-07-01 DOI:10.1016/j.cryogenics.2024.103901
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Abstract

Residual-resistance-ratio (RRR) of Cu stabilizer in REBCO coated conductor is an important design parameter for REBCO magnets. Cu stabilizer with high RRR is especially beneficial for quench protections of REBCO magnets. In this work, we study RRR of electroplated Cu stabilizer in commercial REBCO tapes. We present RRR of over 180 samples measured for the quality assurance programs of REBCO magnet projects at the National High Magnetic Field Laboratory, USA (NHMFL). To investigate the factors that influence RRR, several samples were analyzed extensively by using scanning electron microscopy, secondary ion mass spectroscopy, and inductively coupled plasma mass spectroscopy. We found that RRR is strongly correlated with the grain size of Cu, which suggests that resistivity at low temperatures is dominated by grain boundary resistivity. In addition, low RRR corresponds to high concentration of chlorine impurity. This is explained by that higher chlorine impurity hindered the grain growth in the self-annealing process at room temperature which resulted in smaller grain size and low RRR. Annealing at 300C significantly enlarged the grain size and enhanced RRR. Due to the concern of critical current degradation, however, annealing is not recommended as a practical method to improve RRR of Cu in REBCO tapes.

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商用 REBCO 胶带中铜稳定剂残余电阻比的表征
REBCO 涂层导体中铜稳定剂的残余电阻比 (RRR) 是 REBCO 磁体的一个重要设计参数。高残余电阻率的铜稳定剂尤其有利于 REBCO 磁体的淬火保护。在这项工作中,我们研究了商用 REBCO 磁带中电镀铜稳定剂的电阻率。我们在美国国家高磁场实验室 (NHMFL) 为 REBCO 磁体项目的质量保证计划测量了 180 多个样品的 RRR。为了研究影响 RRR 的因素,我们使用扫描电子显微镜、二次离子质谱和电感耦合等离子体质谱对几个样品进行了广泛分析。我们发现,电阻率与铜的晶粒大小密切相关,这表明低温下的电阻率主要由晶界电阻率决定。此外,低 RRR 与高浓度的氯杂质相对应。这是因为在室温下的自退火过程中,较高的氯杂质阻碍了晶粒的生长,从而导致晶粒尺寸变小,电阻率变低。而在 300C 温度下退火则会明显增大晶粒尺寸,提高 RRR。然而,由于临界电流衰减的问题,退火并不推荐作为提高 REBCO 磁带中铜的 RRR 的实用方法。
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来源期刊
Cryogenics
Cryogenics 物理-热力学
CiteScore
3.80
自引率
9.50%
发文量
0
审稿时长
2.1 months
期刊介绍: Cryogenics is the world''s leading journal focusing on all aspects of cryoengineering and cryogenics. Papers published in Cryogenics cover a wide variety of subjects in low temperature engineering and research. Among the areas covered are: - Applications of superconductivity: magnets, electronics, devices - Superconductors and their properties - Properties of materials: metals, alloys, composites, polymers, insulations - New applications of cryogenic technology to processes, devices, machinery - Refrigeration and liquefaction technology - Thermodynamics - Fluid properties and fluid mechanics - Heat transfer - Thermometry and measurement science - Cryogenics in medicine - Cryoelectronics
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