Styrene Adsortion from Styrene–Water System with Carbon Sorbents

IF 0.6 4区 工程技术 Q4 ENERGY & FUELS Chemistry and Technology of Fuels and Oils Pub Date : 2024-07-19 DOI:10.1007/s10553-024-01713-x
E. V. Komarova, O. Yu. Kupova, T. R. Prosochkina, F. Sh. Vildanov
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Abstract

The adsorption properties of carbon materials for purification of petrochemical systems were predicted digitally. The mechanism of styrene adsorption in pores of various sizes was clarified more precisely and the styrene adsorption energies were calculated with and without taking account of the aqueous medium. The “structure-adsorption activity” relationship was established and the characteristics responsible for increase in adsorption capacity of carbon sorbents were identified: the expedient pore size of the carbon material of the adsorbent was determined to ensure sufficient effectiveness of styrene adsorption from aqueous medium. The experimental studies of styrene adsorption from aqueous medium using commercial AG-3 and BAU carbon sorbents confirm the validity of the established mechanisms.

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使用碳吸附剂从苯乙烯-水系统中去除苯乙烯
以数字方式预测了用于石化系统净化的碳材料的吸附特性。更精确地阐明了苯乙烯在不同大小孔隙中的吸附机理,并计算了考虑和不考虑水介质的苯乙烯吸附能。建立了 "结构-吸附活性 "关系,并确定了导致碳吸附剂吸附容量增加的特征:确定了吸附剂碳材料的适宜孔径,以确保从水介质中充分有效地吸附苯乙烯。使用 AG-3 和 BAU 商用碳吸附剂从水介质中吸附苯乙烯的实验研究证实了既定机制的有效性。
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来源期刊
Chemistry and Technology of Fuels and Oils
Chemistry and Technology of Fuels and Oils 工程技术-工程:化工
CiteScore
0.90
自引率
16.70%
发文量
119
审稿时长
1.0 months
期刊介绍: Chemistry and Technology of Fuels and Oils publishes reports on improvements in the processing of petroleum and natural gas and cracking and refining techniques for the production of high-quality fuels, oils, greases, specialty fluids, additives and synthetics. The journal includes timely articles on the demulsification, desalting, and desulfurizing of crude oil; new flow plans for refineries; platforming, isomerization, catalytic reforming, and alkylation processes for obtaining aromatic hydrocarbons and high-octane gasoline; methods of producing ethylene, acetylene, benzene, acids, alcohols, esters, and other compounds from petroleum, as well as hydrogen from natural gas and liquid products.
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