E. V. Komarova, O. Yu. Kupova, T. R. Prosochkina, F. Sh. Vildanov
{"title":"Styrene Adsortion from Styrene–Water System with Carbon Sorbents","authors":"E. V. Komarova, O. Yu. Kupova, T. R. Prosochkina, F. Sh. Vildanov","doi":"10.1007/s10553-024-01713-x","DOIUrl":null,"url":null,"abstract":"<p>The adsorption properties of carbon materials for purification of petrochemical systems were predicted digitally. The mechanism of styrene adsorption in pores of various sizes was clarified more precisely and the styrene adsorption energies were calculated with and without taking account of the aqueous medium. The “structure-adsorption activity” relationship was established and the characteristics responsible for increase in adsorption capacity of carbon sorbents were identified: the expedient pore size of the carbon material of the adsorbent was determined to ensure sufficient effectiveness of styrene adsorption from aqueous medium. The experimental studies of styrene adsorption from aqueous medium using commercial AG-3 and BAU carbon sorbents confirm the validity of the established mechanisms.</p>","PeriodicalId":9908,"journal":{"name":"Chemistry and Technology of Fuels and Oils","volume":null,"pages":null},"PeriodicalIF":0.6000,"publicationDate":"2024-07-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry and Technology of Fuels and Oils","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1007/s10553-024-01713-x","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
引用次数: 0
Abstract
The adsorption properties of carbon materials for purification of petrochemical systems were predicted digitally. The mechanism of styrene adsorption in pores of various sizes was clarified more precisely and the styrene adsorption energies were calculated with and without taking account of the aqueous medium. The “structure-adsorption activity” relationship was established and the characteristics responsible for increase in adsorption capacity of carbon sorbents were identified: the expedient pore size of the carbon material of the adsorbent was determined to ensure sufficient effectiveness of styrene adsorption from aqueous medium. The experimental studies of styrene adsorption from aqueous medium using commercial AG-3 and BAU carbon sorbents confirm the validity of the established mechanisms.
期刊介绍:
Chemistry and Technology of Fuels and Oils publishes reports on improvements in the processing of petroleum and natural gas and cracking and refining techniques for the production of high-quality fuels, oils, greases, specialty fluids, additives and synthetics. The journal includes timely articles on the demulsification, desalting, and desulfurizing of crude oil; new flow plans for refineries; platforming, isomerization, catalytic reforming, and alkylation processes for obtaining aromatic hydrocarbons and high-octane gasoline; methods of producing ethylene, acetylene, benzene, acids, alcohols, esters, and other compounds from petroleum, as well as hydrogen from natural gas and liquid products.