{"title":"Reactions of the Geminal Dicarbanion Li2[C(SPPh2)2] with Selenium and Tellurium","authors":"Tongtong Wang, Maotong Xu, Douglas Wade Stephan","doi":"10.1002/zaac.202400083","DOIUrl":null,"url":null,"abstract":"The reactions of the dianion [Li2(Et2O)1.5][(SPh2P)2C] 1 with Se and Te were explored and shown to be dependent on the stoichiometry. The species, [Li2(THF)3(SPh2P)2CSe2] 2, [Li2(THF)4(SPh2P)2CSe4C(PPh2S)2] 3, [Li2(THF)3(SPh2P)2CTe2] 4 and [Li2(THF)3Et2O][(SPh2P)2CTe3C(PPh2S)2] 5 have been isolated and structurally characterized. While these products proved to be remarkably sensitive to light and air, the characterization of these products demonstrates that ability of the dianion to intercept short chalcogenide chains of E2‐4.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2024-07-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Zeitschrift für anorganische und allgemeine Chemie","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/zaac.202400083","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
The reactions of the dianion [Li2(Et2O)1.5][(SPh2P)2C] 1 with Se and Te were explored and shown to be dependent on the stoichiometry. The species, [Li2(THF)3(SPh2P)2CSe2] 2, [Li2(THF)4(SPh2P)2CSe4C(PPh2S)2] 3, [Li2(THF)3(SPh2P)2CTe2] 4 and [Li2(THF)3Et2O][(SPh2P)2CTe3C(PPh2S)2] 5 have been isolated and structurally characterized. While these products proved to be remarkably sensitive to light and air, the characterization of these products demonstrates that ability of the dianion to intercept short chalcogenide chains of E2‐4.