Matthieu Hicguet, Prof. Olivier Mongin, Dr. Yann R. Leroux, Dr. Thierry Roisnel, Dr. Fabienne Berrée, Dr. Yann Trolez
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Abstract
We report on the synthesis of two new threaded BODIPYs 5 and 6 in good yields using boron as a gathering atom and a macrocycle with a 2,2’-biphenol unit. In addition to usual techniques, they were characterized by X-ray crystallography. Their electrochemical and optical properties were investigated. In particular, both compounds are highly emissive with photoluminescence quantum yields of 54 and 81 % respectively. In addition, they both show a high photostability.
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