Fabrication of a dye sensitized solar cell using TiO2 sensitized with a mono-carbonyl curcumin analog

IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Journal of the Iranian Chemical Society Pub Date : 2024-07-25 DOI:10.1007/s13738-024-03072-0
Renan Fernando Rigueira, Gideã Taques Tractz, Daniela Aline Barancelli
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Abstract

Dye sensitized solar cell has been shown to be a promising technology for energy conversion. It presented in composition a scaffold material, an electrolyte, a counter electrode and a photosensiting molecule. Due to the costs of the most applied ruthenium-organic material, new compounds are synthesized with the aim of reducing costs. This work describes the synthesis and application of (E)-4-(4-hydroxy-3-methoxyphenyl) but-3-en-2-one (1), a monocarbonyl analog of curcumin, as a photosensiting material in a photovoltaic system. Devices were prepared using TiO2 as scaffold material sensitized with compound 1, graphene as a counter electrode, and I/I3 as an electrolyte. The results showed the possibility of using new organic materials, providing an efficient device in energy conversion, with parameters of Jsc = 0.31 mA cm−2; Voc = 0.54 V, FF = 0.47, PCE = 0.07% and \(\tau_{n}\) = 0.637 s.

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利用单羰基姜黄素类似物敏化的二氧化钛制造染料敏化太阳能电池
染料敏化太阳能电池已被证明是一种前景广阔的能源转换技术。它由支架材料、电解质、对电极和光敏分子组成。由于最常用的钌有机材料成本高昂,人们开始合成新的化合物以降低成本。本研究介绍了(E)-4-(4-羟基-3-甲氧基苯基)丁-3-烯-2-酮(1)的合成和应用,它是姜黄素的单羰基类似物,可用作光伏系统中的光敏材料。研究人员以化合物 1 增敏的二氧化钛为支架材料,以石墨烯为对电极,以 I-/I3- 为电解质制备了装置。结果表明,使用新型有机材料可以提供高效的能量转换装置,其参数为:Jsc = 0.31 mA cm-2;Voc = 0.54 V;FF = 0.47;PCE = 0.07%;\(\tau_{n}\) = 0.637 s。
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来源期刊
CiteScore
4.40
自引率
8.30%
发文量
230
审稿时长
5.6 months
期刊介绍: JICS is an international journal covering general fields of chemistry. JICS welcomes high quality original papers in English dealing with experimental, theoretical and applied research related to all branches of chemistry. These include the fields of analytical, inorganic, organic and physical chemistry as well as the chemical biology area. Review articles discussing specific areas of chemistry of current chemical or biological importance are also published. JICS ensures visibility of your research results to a worldwide audience in science. You are kindly invited to submit your manuscript to the Editor-in-Chief or Regional Editor. All contributions in the form of original papers or short communications will be peer reviewed and published free of charge after acceptance.
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