Modified 2,3-bis(thienyl)quinoxaline fluorophores as potential chemosensors

IF 1.7 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Russian Chemical Bulletin Pub Date : 2024-07-26 DOI:10.1007/s11172-024-4292-9
T. N. Moshkina, A. E. Kopotilova, D. A. Gazizov, M. I. Valieva, E. S. Starnovskaya, A. A. Kalinichev, D. S. Kopchuk, E. V. Nosova, V. N. Charushin
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Abstract

2,3-Bis[5-(pyren-1-yl)thiophen-2-yl]quinoxalines and 2,3-bis{5-[4-(9H-carbazol-9-yl)phenyl]thiophen-2-yl}pyrazino[2,3-f][1,10]phenanthroline were synthesized. One- and two-photon absorption and emission of the compounds were studied, the cross sections of the two-photon absorption were found to be equal to 101–476 GM in THF. Fluorescent responses of pyrene-containing fluorophores and dipyrido-annelated quinoxaline to nitroaromatic compounds and metal cations, respectively, were investigated.

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作为潜在化学传感器的改性 2,3-双(噻吩基)喹喔啉荧光团
合成了 2,3-双[5-(芘-1-基)噻吩-2-基]喹喔啉和 2,3-双{5-[4-(9H-咔唑-9-基)苯基]噻吩-2-基}吡嗪并[2,3-f][1,10]菲罗啉。对这些化合物的单光子和双光子吸收和发射进行了研究,发现在 THF 中双光子吸收的截面等于 101-476 GM。研究了含芘荧光团和二吡啶通道喹喔啉分别对硝基芳香族化合物和金属阳离子的荧光反应。
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来源期刊
Russian Chemical Bulletin
Russian Chemical Bulletin 化学-化学综合
CiteScore
2.70
自引率
47.10%
发文量
257
审稿时长
3-8 weeks
期刊介绍: Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections: General and Inorganic Chemistry; Physical Chemistry; Organic Chemistry; Organometallic Chemistry; Chemistry of Natural Compounds and Bioorganic Chemistry.
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