Research on the Optimization of the Heating Effect of Lithium-Ion Batteries at a Low Temperature Based on an Electromagnetic Induction Heating System

IF 4.7 3区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC ACS Applied Electronic Materials Pub Date : 2024-07-25 DOI:10.3390/en17153678
Borui Wang, Mingyin Yan
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Abstract

Based on an electromagnetic induction heating system that was recently developed in a previous work, an orthogonal test with three elements and nine levels was carried out to improve the heating effect of the system. This was intended to achieve a balance between the heating rate and temperature uniformity, where the electrochemical and thermal behaviors of the heated lithium-ion battery could be characterized by a high-accuracy electrochemical–thermal coupling model. This was validated against constant-current discharge and HPPC test data at room temperature and different low temperatures. Under the optimal parameter combination that was found in the orthogonal test, the battery temperature could rise to 293.15 K from 243.15 K in 494 s, with a maximum temperature rise rate of 0.133 K·s−1. The temperature difference after heating reached 4.21 K, which resulted from the heat conductivity of the battery material due to the skin depth of the battery shell and the material properties inside the battery. Due to the internal resistance, which decreased to no more than a quarter of the low-temperature level, both the usable energy and pulse power were increased more than 2.5 and 3 times, respectively. The enhancement of the energy output ability could provide a greater cruise range and improved dynamics for electric vehicles. The capacity calibration results obtained during the heating cycles indicated that there was only a 3.61% reduction in capacity retention after 120 repetitive heating cycles, which was 0.008 Ah below the normal cycle at 293.15 K, even compared with room-temperature capacity calibration, thus reducing the effect on the battery’s lifetime. Therefore, the electromagnetic induction heating system with a heating strategy could achieve a beneficial compromise between the temperature rise behavior, cycle lifetime, and working ability, indicating considerable potential for the optimization of the heating effect.
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基于电磁感应加热系统的锂离子电池低温加热效果优化研究
基于先前工作中最新开发的电磁感应加热系统,进行了三元素九级正交试验,以改善系统的加热效果。这样做的目的是在加热速率和温度均匀性之间取得平衡,通过高精度的电化学-热耦合模型来表征加热锂离子电池的电化学和热行为。该模型根据室温和不同低温下的恒流放电和 HPPC 测试数据进行了验证。在正交试验中找到的最佳参数组合下,电池温度可在 494 秒内从 243.15 K 升至 293.15 K,最大升温速率为 0.133 K-s-1。加热后的温差达到了 4.21 K,这是由于电池外壳的表皮深度和电池内部的材料特性所导致的电池材料导热性所造成的。由于内阻下降到不超过低温时的四分之一,可用能量和脉冲功率分别提高了 2.5 倍和 3 倍以上。能量输出能力的提高可为电动汽车提供更大的巡航范围和更好的动力性。加热循环期间获得的容量校准结果表明,即使与室温容量校准相比,经过 120 次重复加热循环后,容量保持率仅降低了 3.61%,比 293.15 K 下的正常循环低 0.008 Ah,从而降低了对电池寿命的影响。因此,采用加热策略的电磁感应加热系统可以在温升行为、循环寿命和工作能力之间实现有益的折衷,这表明加热效果的优化具有相当大的潜力。
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来源期刊
CiteScore
7.20
自引率
4.30%
发文量
567
期刊介绍: ACS Applied Electronic Materials is an interdisciplinary journal publishing original research covering all aspects of electronic materials. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials science, engineering, optics, physics, and chemistry into important applications of electronic materials. Sample research topics that span the journal's scope are inorganic, organic, ionic and polymeric materials with properties that include conducting, semiconducting, superconducting, insulating, dielectric, magnetic, optoelectronic, piezoelectric, ferroelectric and thermoelectric. Indexed/​Abstracted: Web of Science SCIE Scopus CAS INSPEC Portico
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