Synergistic Effects in BFO@NiCoS@CNT//AC Nanocomposite for High-Capacity Energy Storage Systems

M. Waris, Muhammad Azhar Mumtaz, Amir Afzal, Sohail Mumtaz, Nimra Muzaffar, Waqas Iqbal, Areej S. Alqarni
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Abstract

Here, we synthesized a nanocomposite electrode material for high-performance asymmetric supercapacitor devices (ASCD) made of bismuth ferrite (BFO) nanocomposite and nickel cobalt sulfide with carbon nanotubes (NiCoS@CNT). To fabricate the BFO@NiCoS@CNT nanocomposite, a simple hydrothermal process was used. Electrochemical impedance spectroscopy, galvanostatic charge/discharge measurements, and cyclic voltammetry were used to evaluate the electrochemical experiments. At a scan speed of 5 mVs-1, the BFO@NiCoS@CNT nanocomposite exhibited a specific capacitance of 2890 Fg-1, surpassing pure BFO@NiCoS. Furthermore, the nanocomposite displayed excellent cyclic stability, retaining around 87.8% of its capacity retention even after 5000 cycles. Another notable property is its energy density (Ed) of 71 Whkg-1 at the power density (Pd) of 2400 Wkg-1. Based on these promising findings, BFO@NiCoS@CNT nanocomposite might be used to fabricate electrodes for high-performance hybrid supercapacitors. Our research indicates that this is the first report of a BFO@NiCoS@CNT nanocomposite used as an asymmetric supercapacitor.
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用于大容量储能系统的 BFO@NiCoS@CNT//AC 纳米复合材料的协同效应
在这里,我们合成了一种用于高性能非对称超级电容器器件(ASCD)的纳米复合电极材料,该材料由铁氧体铋(BFO)纳米复合材料和硫化镍钴与碳纳米管(NiCoS@CNT)组成。为了制造 BFO@NiCoS@CNT 纳米复合材料,采用了一种简单的水热工艺。电化学阻抗谱、电静态充放电测量和循环伏安法被用于评估电化学实验。在 5 mVs-1 的扫描速度下,BFO@NiCoS@CNT 纳米复合材料的比电容为 2890 Fg-1,超过了纯 BFO@NiCoS。此外,该纳米复合材料还显示出卓越的循环稳定性,即使在循环 5000 次后,其容量保持率仍高达 87.8%。另一个值得注意的特性是,在功率密度(Pd)为 2400 Wkg-1 时,其能量密度(Ed)为 71 Whkg-1。基于这些有前景的发现,BFO@NiCoS@CNT 纳米复合材料可用于制造高性能混合超级电容器的电极。我们的研究表明,这是首次报道 BFO@NiCoS@CNT 纳米复合材料用作不对称超级电容器。
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