Cleaning the Electroerosive Machining Wastewater with some Polyacrylamide-Based Flocculants

S. Boruk, Igor Winkler
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Abstract

The granulometric composition of the metal/scale suspensions formed at electroerosive machining (EEM) of metal items made of the ST-10 steel has been determined to evaluate the need for a flocculant for the suspension particles extraction and decontamination of the machining working fluid. Even though most suspension particles are large enough and quickly self-precipitate, some particles are too small (sized 6 µm or less) and form quite stable suspensions, requiring additional flocculants to be extracted. Pure polyacrylamide with a molecular weight of 4-5*106 atomic units and an anionic polymer flocculant BESFLOC-4041 were considered as decontamination agents for the metal/scale suspensions. It was found that the latter agent is more effective, and it ensures the effective decontamination of an EEM working fluid. An admixture of 0.05 g/L of BESFLOC-4041 ensures effective clarification (with the decontamination efficiency of 90-95 %) of the metal/scale suspension with a dispersed phase concentration of up to 1.0 g/L. The flocculation efficiency of polyacrylamimde is lower (67-85 %) and its best performance is achieved at the concentration of 0.08 g/L.
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用一些聚丙烯酰胺基絮凝剂净化电解加工废水
对 ST-10 钢制金属制品进行电解加工(EEM)时形成的金属/鳞片悬浮液的粒度组成进行了测定,以评估是否需要使用絮凝剂来提取悬浮颗粒和净化加工工作液。尽管大多数悬浮颗粒足够大,并能很快自沉淀,但有些颗粒太小(尺寸为 6 微米或更小),形成的悬浮液相当稳定,需要额外的絮凝剂来提取。分子量为 4-5*106 原子单位的纯聚丙烯酰胺和阴离子聚合物絮凝剂 BESFLOC-4041 被视为金属/鳞片悬浮液的去污剂。研究发现,后者更为有效,可确保 EEM 工作液得到有效净化。掺入 0.05 克/升的 BESFLOC-4041 可确保有效澄清分散相浓度高达 1.0 克/升的金属/鳞片悬浮液(去污效率为 90-95%)。聚丙烯酰胺的絮凝效率较低(67-85 %),在浓度为 0.08 g/L 时性能最佳。
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