Synthesis and tribological assessment of oil-based nanolubricants blended with nano-zeolite for steel–steel contact

Lin Zhu, Yunyun Sun, Shijing Wu
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Abstract

This study aims to synthesize zeolite with nano-sized morphology and investigate the tribological performance of nano-zeolite as a lubricating additive dispersed in an oil-based lubricant. Tribological tests were performed and morphologies of wear tracks were characterized to investigate the friction reduction and anti-wear properties of zeolite, respectively. The lubrication mechanism was discussed by illustrating the effects of concentration and particle size on the tribological behavior of zeolite. The optimal concentration of nano-zeolite to improve the tribological performance of the base oil was 2 wt.%, which exhibited a friction reduction of 34.3%. Zeolite particles with larger diameters showed better dispersion stability but worse lubrication performance, which could be concluded from the decrease in the friction reduction ratio. Moreover, the friction coefficient under the lubrication of zeolite at 200°C was 15.8% lower than that of the pure base oil, demonstrating the thermal stability of zeolite. Notably, the application of zeolite resulted in an increase in wear depth due to the occurrence of the three-body abrasion, while the surface asperities of the counterpart were also smoothed in the meantime. This work demonstrates the potential of nano-zeolite to enhance the tribological performance of oil-based lubricants in industrial applications, which could be attributed to their porous structure, lipophilicity, and chemical–thermal stability.
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用于钢-钢接触的油基纳米润滑剂与纳米沸石混合物的合成与摩擦学评估
本研究旨在合成具有纳米尺寸形态的沸石,并研究纳米沸石作为润滑添加剂分散在油基润滑剂中的摩擦学性能。通过摩擦学测试和磨损痕迹的形态特征,分别研究了沸石的减摩和抗磨性能。通过说明浓度和粒度对沸石摩擦学行为的影响,讨论了润滑机理。纳米沸石改善基础油摩擦学性能的最佳浓度为 2 wt.%,其摩擦降低率为 34.3%。直径较大的沸石颗粒显示出较好的分散稳定性,但润滑性能较差,这可以从摩擦降低率的下降中得出结论。此外,在 200°C 温度下,沸石润滑下的摩擦系数比纯基础油低 15.8%,这表明了沸石的热稳定性。值得注意的是,由于发生了三体磨损,沸石的应用导致了磨损深度的增加,同时对应材料的表面粗糙度也被磨平。这项工作证明了纳米沸石在工业应用中提高油基润滑剂摩擦学性能的潜力,这可能归功于其多孔结构、亲油性和化学热稳定性。
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