Single and Multi-Mineral Classification using Dual-Band Raman Spectroscopy for Planetary Surface Missions

IF 4.7 Q2 MATERIALS SCIENCE, BIOMATERIALS ACS Applied Bio Materials Pub Date : 2024-07-19 DOI:10.2138/am-2023-9072
Timothy K. Johnsen, Virginia C. Gulick
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Abstract

Planetary surface missions have greatly benefitted from intelligent systems capable of semi-autonomous navigation and surveying. However, instruments onboard these missions are not similarly equipped with automated science analysis classifiers onboard rovers, which can further improve scientific yield and autonomy. Here, we present both single- and multi-mineral autonomous classifiers integrated using the results from a co-registered dual-band Raman spectrometer. This instrument consecutively irradiates the same spot size on the same sample using two excitation lasers of different wavelengths (532 nm and 785 nm). We identify the presence of mineral groups: pyroxene, olivine, potassium feldspar, quartz, mica, gypsum, and plagioclase, in 191 rocks. These minerals are among the major rock forming mineral groups and so their presence or absence within a sample is key for understanding rock composition and the environment in which it formed. We present machine learning methods used to train classifiers and leverage the multiple modalities of the dual-band Raman spectrometer. When testing on a novel sample set for single-mineral classification, we show accuracy scores up to 100% (varying by mineral), with a total classification rate (over all minerals) of 91%. When testing on a novel set of samples for multi-mineral classification, we show accuracy scores up to 96%, with a total classification rate of 73%. We end with several hypothesis tests, that demonstrate that dual-band Raman spectroscopy is more robust and improves the scientific yield for mineral classification over single-band spectroscopy, especially when combined with our multimodal neural network.
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利用双波段拉曼光谱对行星表面飞行任务中的单矿物和多矿物进行分类
行星表面任务大大受益于能够半自主导航和勘测的智能系统。然而,这些任务所搭载的仪器并没有像漫游车那样配备自动科学分析分类器,而这种分类器可以进一步提高科学成果和自主性。在这里,我们介绍了利用共注册双波段拉曼光谱仪的结果集成的单矿物和多矿物自主分类器。该仪器使用两个不同波长(532 nm 和 785 nm)的激发激光连续照射同一样品上的相同光斑。我们确定了 191 种岩石中存在的矿物群:辉石、橄榄石、钾长石、石英、云母、石膏和斜长石。这些矿物是形成岩石的主要矿物群,因此它们在样本中的存在与否是了解岩石成分及其形成环境的关键。我们介绍了用于训练分类器的机器学习方法,并充分利用了双波段拉曼光谱仪的多种模式。在对新样本集进行单矿物分类测试时,我们发现准确率高达 100%(因矿物而异),总分类率(所有矿物)为 91%。在对一组新样本进行多矿物分类测试时,我们发现准确率高达 96%,总分类率为 73%。最后,我们进行了几项假设检验,结果表明双波段拉曼光谱比单波段光谱更稳健,更能提高矿物分类的科学性,尤其是与我们的多模态神经网络相结合时。
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来源期刊
ACS Applied Bio Materials
ACS Applied Bio Materials Chemistry-Chemistry (all)
CiteScore
9.40
自引率
2.10%
发文量
464
期刊介绍: ACS Applied Bio Materials is an interdisciplinary journal publishing original research covering all aspects of biomaterials and biointerfaces including and beyond the traditional biosensing, biomedical and therapeutic applications. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrates knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important bio applications. The journal is specifically interested in work that addresses the relationship between structure and function and assesses the stability and degradation of materials under relevant environmental and biological conditions.
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