Synthesis of carbon nanotube–iron oxide and silver nanocomposites as photocatalyst in removing carcinogenic aromatic dyes

Noor Haider Abdul Ali Al-Shawi, Zh. Ebrahiminejad, Somayeh Asgary
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Abstract

In this research, a three-component composite was synthesized by using carbon nanotube as the background phase. Iron oxide phase with high magnetization and low coercivity (with particle size of 200 nm) has been coated on the carbon nanotubes. Then, the silver nanoparticles were coated on a conductive and magnetized substrate by an ultrasonic method. Semiconductor photocatalys is a favorable route for the degradation of organic pollutants. Ultraviolet–visible spectrophotometry has been used to investigate the photocatalytic properties of synthesized nanocomposite and control of their dye degradation on methyl blue, methyl orange and methyl red. The obtained nanocomposite is easily collected due to its magnetic property and does not pose a risk to environmental waters. The dye degradation degree has been compared for the produced nanocomposite. The experimental results confirmed that methyl red shows the greatest amount of degradation within 1 h, which was about 90 %, methyl orange shows about 80 %, and methyl blue shows the lowest degradation, around 60 %.
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合成碳纳米管-氧化铁和银纳米复合材料,作为去除致癌芳香族染料的光催化剂
本研究以碳纳米管为背景相,合成了一种三组分复合材料。在碳纳米管上涂覆了具有高磁化率和低矫顽力的氧化铁相(粒径为 200 nm)。然后,通过超声波方法在导电和磁化基底上涂覆银纳米粒子。半导体光催化是降解有机污染物的有利途径。利用紫外-可见分光光度法研究了合成纳米复合材料的光催化性能,并控制其对甲基蓝、甲基橙和甲基红染料的降解。获得的纳米复合材料因其磁性而易于收集,不会对环境水体造成危害。比较了所制备纳米复合材料的染料降解程度。实验结果证实,甲基红在 1 小时内的降解量最大,约为 90%;甲基橙约为 80%;甲基蓝的降解量最小,约为 60%。
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