Recent advances in electrochemiluminescence based on polymeric luminophores

IF 8.9 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Chinese Chemical Letters Pub Date : 2025-05-01 Epub Date: 2024-07-18 DOI:10.1016/j.cclet.2024.110284

Sijia Zhou , Tianyi Zhou , Yuhua Hou , Wang Li , Yanfei Shen , Songqin Liu , Kaiqing Wu , Yuanjian Zhang

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Abstract

Developing efficient, non-toxic, and low-cost emitters is a key issue in promoting the applications of electrochemiluminescence (ECL). Among varied ECL emitters, polymeric emitters are attracting dramatically increasing interest due to tunable structure, large surface area, brilliant transfer capability, and sustainable raw materials. In this review, we present a general overview of recent advances in developing polymeric luminophores, including their structural and synthetic methodologies. Methods rooted in straightforward unique structural modulation have been comprehensively summarized, aiming at enhancing the efficiency of ECL along with the underlying kinetic mechanisms. Moreover, as several conjugated polymers were just discovered in recent years, promising prospects and perspectives have also been deliberated. The insight of this review may provide a new avenue for helping develop advanced conjugated polymer ECL emitters and decode ECL applications.

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基于聚合物发光体的电化学发光技术的最新进展

开发高效、无毒、低成本的发光材料是促进电化学发光技术应用的关键问题。在各种各样的ECL发射体中，聚合物发射体由于其可调谐的结构、大的表面积、出色的转移能力和可持续的原材料而引起了人们越来越多的兴趣。在这篇综述中，我们介绍了聚合物发光团的最新进展，包括它们的结构和合成方法。本文综合总结了基于简单独特结构调制的方法，旨在提高ECL的效率和潜在的动力学机制。此外，由于近年来新发现的几种共轭聚合物，对其应用前景进行了展望。本文综述的见解为开发先进的共轭聚合物ECL发射器和解码ECL应用提供了新的途径。

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来源期刊

Chinese Chemical Letters 化学-化学综合

CiteScore

14.10

自引率

15.40%

发文量

8969

审稿时长

1.6 months

期刊介绍： Chinese Chemical Letters (CCL) (ISSN 1001-8417) was founded in July 1990. The journal publishes preliminary accounts in the whole field of chemistry, including inorganic chemistry, organic chemistry, analytical chemistry, physical chemistry, polymer chemistry, applied chemistry, etc.Chinese Chemical Letters does not accept articles previously published or scheduled to be published. To verify originality, your article may be checked by the originality detection service CrossCheck.