Recycling of Nd−Fe−B sintered magnets into a single phase by solvothermal treatment and CaH2 reduction-diffusion

IF 3 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Materialia Pub Date : 2024-08-01 DOI:10.1016/j.mtla.2024.102189
A. Chetouani, F. Richomme, J.M. Le Breton
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Abstract

Recycling computer hard disk drives from Waste Electrical and Electronic Equipment (WEEE) has been achieved according to a two-step approach that combines solvothermal treatment and CaH2 reduction-diffusion, resulting in the production of a single-phase material. The magnets underwent solvothermal treatment, followed by CaH2 reduction at varying temperatures (200°C, 250°C and 300°C). We examined the impact of CaH2 as a reducing agent on the final product, using X-ray diffraction, Mössbauer spectrometry and SQUID magnetometry. After the solvothermal treatment, the powder contains both Nd2Fe14BHx and Nd(OH)3 phases. At 200°C, Nd(OH)3 was reduced without degradation of the magnetic Nd2Fe14BHx phase, as confirmed by Mössbauer spectrometry. Furthermore, an analysis of the magnetic properties indicates an increase in magnetization after CaO removal, confirming its successful elimination.

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通过溶热处理和 CaH2 还原扩散将 Nd-Fe-B 烧结磁体回收为单相
从废弃电子电气设备(WEEE)中回收电脑硬盘驱动器的工作是通过溶热处理和 CaH2 还原-扩散相结合的两步法实现的,从而生产出一种单相材料。磁体经过溶热处理,然后在不同温度(200°C、250°C 和 300°C)下进行 CaH2 还原。我们使用 X 射线衍射、莫斯鲍尔光谱仪和 SQUID 磁强计研究了 CaH2 作为还原剂对最终产品的影响。经溶热处理后,粉末中同时含有 Nd2Fe14BHx 和 Nd(OH)3 两相。在 200°C 时,Nd(OH)3 被还原,而磁性 Nd2Fe14BHx 相却没有退化,这一点已被莫斯鲍尔能谱分析证实。此外,对磁性能的分析表明,去除 CaO 后磁化率增加,证明成功消除了 CaO。
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来源期刊
Materialia
Materialia MATERIALS SCIENCE, MULTIDISCIPLINARY-
CiteScore
6.40
自引率
2.90%
发文量
345
审稿时长
36 days
期刊介绍: Materialia is a multidisciplinary journal of materials science and engineering that publishes original peer-reviewed research articles. Articles in Materialia advance the understanding of the relationship between processing, structure, property, and function of materials. Materialia publishes full-length research articles, review articles, and letters (short communications). In addition to receiving direct submissions, Materialia also accepts transfers from Acta Materialia, Inc. partner journals. Materialia offers authors the choice to publish on an open access model (with author fee), or on a subscription model (with no author fee).
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