Carbon dots-Zno/TiO2 ternary nanocomposite as a proficient material to enhance the performance of natural DSSC

Abstract

A novel sustainable approach for enhancing the efficiency of dye-sensitized solar cells (DSSCs) involves the utilization of a combination of ZnO and carbon dots (CDs) derived from Citrus medica fruit extract, along with microwave-synthesized TiO₂ nanoparticles for the preparation of the photoanode. Natural dyes such as Hibiscus rosa-sinensis and Allium Cepa peel are employed as sensitizers to reduce production costs. This co-activation method has demonstrated a significant improvement in the output parameters of the devices. Notably, the photoanode co-activated with ZnO-CD composite (ZnO-CD/TiO₂) exhibits the most favorable output parameters when combined with Hibiscus rosa-sinensis dye (open circuit voltage (Voc) = 0.80 V, short circuit current density (Jsc) = 6.62 mA/cm², fill factor (FF) = 64.20 %, photo conversion efficiency (PCE) = 3.40 %) and Allium Cepa peel dye (Voc = 0.81 V, Jsc = 6.79 mA/cm², FF = 65.70 %, PCE = 3.61 %). When paired with Allium Cepa dye, the CD modified photoanode (CD/TiO₂) offers Voc = 0.73 V, Jsc = 6.64 mA/cm², FF = 61.27 % and PCE = 2.97 %. Similarly, when combined with Hibiscus rosa-sinensis dye, the output parameters of the CD/TiO₂ photoanode are Voc = 0.72 V, Jsc = 6.54 mA/cm², FF = 64.4 % and PCE = 3.03 %. In comparison to all tested devices, the unmodified photoanode (TiO₂) displayed the lowest performance, with parameters such as Voc = 0.59 V, Jsc = 6.45 mA/cm², FF = 52.5 %, PCE = 2.10 % using Allium Cepa peel dye, and Voc = 0.66 V, Jsc = 6 mA/cm², FF = 51.60 %, PCE = 2.04 % using Hibiscus rosa-sinensis dye. Furthermore, the co-activation process has been shown to enhance the stability of the devices. While the unmodified photoanodes ceased to operate after eight days, the ZnO-CD composite co-activated photoanodes retained their initial efficiencies up to 61.50 % and 68.53 % with the Allium Cepa peel dye and Hibiscus rosa-sinensis dye, respectively. Therefore, this study underscores the potential of the synthesized composite material in enhancing the performance of natural DSSCs.