{"title":"Phosphate adsorption characteristics of CeO<sub>2</sub>-loaded, Eucommia ulmoides leaf residue biochar.","authors":"Yufang Yue, Zixing Zeng, Yu Zhou, Wenyong Hu","doi":"10.1016/j.envpol.2024.124657","DOIUrl":null,"url":null,"abstract":"<p><p>In this study, a Ce-loading biochar (Ce-BC) was synthesized by the optimal modification method of pre-pyrolysis impregnation, a pyrolysis temperature at 600 °C, and a CeCl<sub>3</sub> concentration of 1.00 mol L<sup>-1</sup> for efficient adsorption phosphorus (P) from wastewater. The results revealed that Ce-BC could achieve a maximum P removal rate of 100% under specific conditions: an adsorbent concentration of 2.00 g L<sup>-1</sup>, an initial solution pH of 3.00, an adsorption temperature of 25 °C, and an initial P concentration of 20.00 mg L<sup>-1</sup>. The adsorption process followed the quasi-secondary kinetic model, suggesting the Ce-BC was particularly effective in acidic environments. Meanwhile, Ce-BC has a strong resistance to anion interference and good cycling performance (the P adsorption capacity of Ce-BC was 59.77% of its initial value after four cycles). Field emission scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and X-ray diffraction (XRD) indicated that Ce-BC contained a porous structure and rich functional groups (hydroxyl and carboxyl), and compounds of CeO<sub>2</sub> and MgCeO<sub>3</sub> were formed. The Ce loading favored the exchange with P through ligands, inner-sphere complexation, ion exchange, and electrostatic interaction to form inner-sphere complex-cerium P (CePO<sub>4</sub>), and the surface complex of Ce-O-P replaced O-H. In addition, the Ce-BC adsorption columns substantially affected P removal in actual wastewater. Overall, Ce-BC is a promising material for the treating P-containing acidic wastewater.</p>","PeriodicalId":311,"journal":{"name":"Environmental Pollution","volume":null,"pages":null},"PeriodicalIF":7.6000,"publicationDate":"2024-08-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Environmental Pollution","FirstCategoryId":"93","ListUrlMain":"https://doi.org/10.1016/j.envpol.2024.124657","RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
引用次数: 0
Abstract
In this study, a Ce-loading biochar (Ce-BC) was synthesized by the optimal modification method of pre-pyrolysis impregnation, a pyrolysis temperature at 600 °C, and a CeCl3 concentration of 1.00 mol L-1 for efficient adsorption phosphorus (P) from wastewater. The results revealed that Ce-BC could achieve a maximum P removal rate of 100% under specific conditions: an adsorbent concentration of 2.00 g L-1, an initial solution pH of 3.00, an adsorption temperature of 25 °C, and an initial P concentration of 20.00 mg L-1. The adsorption process followed the quasi-secondary kinetic model, suggesting the Ce-BC was particularly effective in acidic environments. Meanwhile, Ce-BC has a strong resistance to anion interference and good cycling performance (the P adsorption capacity of Ce-BC was 59.77% of its initial value after four cycles). Field emission scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and X-ray diffraction (XRD) indicated that Ce-BC contained a porous structure and rich functional groups (hydroxyl and carboxyl), and compounds of CeO2 and MgCeO3 were formed. The Ce loading favored the exchange with P through ligands, inner-sphere complexation, ion exchange, and electrostatic interaction to form inner-sphere complex-cerium P (CePO4), and the surface complex of Ce-O-P replaced O-H. In addition, the Ce-BC adsorption columns substantially affected P removal in actual wastewater. Overall, Ce-BC is a promising material for the treating P-containing acidic wastewater.
期刊介绍:
Environmental Pollution is an international peer-reviewed journal that publishes high-quality research papers and review articles covering all aspects of environmental pollution and its impacts on ecosystems and human health.
Subject areas include, but are not limited to:
• Sources and occurrences of pollutants that are clearly defined and measured in environmental compartments, food and food-related items, and human bodies;
• Interlinks between contaminant exposure and biological, ecological, and human health effects, including those of climate change;
• Contaminants of emerging concerns (including but not limited to antibiotic resistant microorganisms or genes, microplastics/nanoplastics, electronic wastes, light, and noise) and/or their biological, ecological, or human health effects;
• Laboratory and field studies on the remediation/mitigation of environmental pollution via new techniques and with clear links to biological, ecological, or human health effects;
• Modeling of pollution processes, patterns, or trends that is of clear environmental and/or human health interest;
• New techniques that measure and examine environmental occurrences, transport, behavior, and effects of pollutants within the environment or the laboratory, provided that they can be clearly used to address problems within regional or global environmental compartments.