Production of magnetic photocatalysts from TiO2, Fe(NO3)3 and sucrose and their application for the degradation of model organic contaminants

Abstract

BACKGROUND

Photocatalysis is an efficient method for the removal of organic contaminants in wastewater. In this study, different magnetic photocatalysts for the degradation of organic compounds were prepared.

RESULTS

Ti/C/Fe photocatalysts were prepared by supporting TiO₂ (20, 40 and 60% w/w) on a carbon/iron oxide (C/Fe) magnetic carrier. Characterization via Raman spectroscopy, X-ray diffractometry, thermal analysis, X-ray fluorescence, scanning electron microscopy and energy-dispersive X-ray spectroscopy/elemental mapping and magnetic property analysis by vibrating-sample magnetometry confirmed the presence of TiO₂, Fe₃O₄, Fe₃C and char in the photocatalysts as well as their magnetic properties. The results of specific surface area analysis showed that the C/Fe support had a surface area of 183 m² g⁻¹ and that this area decreased with an increasing amount of supported TiO₂, reaching up to 129 m² g⁻¹. Diffuse reflectance spectroscopy characterization revealed that the bandgap values obtained for the photocatalysts (Ti/C/Fe) were lower than 3.2 eV. The prepared photocatalysts showed high efficiency in degrading the contaminants Remazol Black (RB5) (99%), paracetamol (77%) and phenol (90%). Recovery and reuse experiments using RB5 showed that after the fourth reaction, the photocatalytic efficiency was reduced by 50%, and the recovery reached up to 70%. Sedimentation kinetics showed that while only 6% of the TiO₂ was deposited, up to 89% of the photocatalysts were deposited.

CONCLUSIONS

These results indicate that the photocatalysts showed excellent photocatalytic efficiency for different contaminants and can be easily and quickly separated from the reaction medium by magnetic separation. © 2024 Society of Chemical Industry (SCI).