Sh. N. Zhurakulov, E. A. Bainazarov, V. I. Vinogradova, M. A. Eshonov, K. K. Turgunov, B. Tashkhodzhaev, Zh. K. Namazbaeva
{"title":"Oxidation of Quinoline Alkaloids Bucharaine, Foliosidine, Evoxine, and Dubinidine by Periodic Acid","authors":"Sh. N. Zhurakulov, E. A. Bainazarov, V. I. Vinogradova, M. A. Eshonov, K. K. Turgunov, B. Tashkhodzhaev, Zh. K. Namazbaeva","doi":"10.1007/s10600-024-04410-7","DOIUrl":null,"url":null,"abstract":"<p>The effect of periodic acid on oxidation of the quinoline alkaloids bucharaine, foliosidine, evoxine, and dubinidine was studied as a function of their structures and the reaction conditions. Periodic acid in dilute aqueous solutions was shown to form stable gem-diols. The use of a large excess of HIO<sub>4</sub> formed gem-diols and aldehydes. O-Methyl derivatives were obtained in aqueous MeOH solutions.</p>","PeriodicalId":514,"journal":{"name":"Chemistry of Natural Compounds","volume":null,"pages":null},"PeriodicalIF":0.8000,"publicationDate":"2024-08-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry of Natural Compounds","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1007/s10600-024-04410-7","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MEDICINAL","Score":null,"Total":0}
引用次数: 0
Abstract
The effect of periodic acid on oxidation of the quinoline alkaloids bucharaine, foliosidine, evoxine, and dubinidine was studied as a function of their structures and the reaction conditions. Periodic acid in dilute aqueous solutions was shown to form stable gem-diols. The use of a large excess of HIO4 formed gem-diols and aldehydes. O-Methyl derivatives were obtained in aqueous MeOH solutions.
期刊介绍：
Chemistry of Natural Compounds publishes reviews and general articles about the structure of different classes of natural compounds, the chemical characteristics of botanical families, genus, and species, to establish the comparative laws and connection between physiological activity and the structure of substances.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
