{"title":"Capacitance Measurement for Evaluating the Initial Top-Electrode-Damage-Induced Degradation of Organic Devices","authors":"Chunqin Zhu, Guangrui Zhu, Ya Zhao, Ruichen Yi, Xiaoyuan Hou, Jiajun Qin","doi":"10.1021/acsmaterialslett.4c01103","DOIUrl":null,"url":null,"abstract":"The formation of bubbles and fractures on the top electrode surface is one of the key factors that leads to the degradation of organic devices. This degradation can be directly observed through optical microscopy but only in low spatial resolution of several micrometers due to limited optical contrast between the bubbles and their surroundings. Here, we present a nonintrusive capacitance method to characterize electrode damage with improved accuracy and testing efficiency. For serious degradation with a large damage area at the top electrode (almost more than 10 μm), the relative drop in capacitance after degradation is consistent with the results derived by optical microscopy. For initial degradation with a damage area below the resolution of optical microscopy (even less than 1 μm), our proposed capacitance method still works well, which is validated by atomic force microscopy results.","PeriodicalId":9,"journal":{"name":"ACS Catalysis ","volume":null,"pages":null},"PeriodicalIF":11.3000,"publicationDate":"2024-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Catalysis ","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/acsmaterialslett.4c01103","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The formation of bubbles and fractures on the top electrode surface is one of the key factors that leads to the degradation of organic devices. This degradation can be directly observed through optical microscopy but only in low spatial resolution of several micrometers due to limited optical contrast between the bubbles and their surroundings. Here, we present a nonintrusive capacitance method to characterize electrode damage with improved accuracy and testing efficiency. For serious degradation with a large damage area at the top electrode (almost more than 10 μm), the relative drop in capacitance after degradation is consistent with the results derived by optical microscopy. For initial degradation with a damage area below the resolution of optical microscopy (even less than 1 μm), our proposed capacitance method still works well, which is validated by atomic force microscopy results.
期刊介绍:
ACS Catalysis is an esteemed journal that publishes original research in the fields of heterogeneous catalysis, molecular catalysis, and biocatalysis. It offers broad coverage across diverse areas such as life sciences, organometallics and synthesis, photochemistry and electrochemistry, drug discovery and synthesis, materials science, environmental protection, polymer discovery and synthesis, and energy and fuels.
The scope of the journal is to showcase innovative work in various aspects of catalysis. This includes new reactions and novel synthetic approaches utilizing known catalysts, the discovery or modification of new catalysts, elucidation of catalytic mechanisms through cutting-edge investigations, practical enhancements of existing processes, as well as conceptual advances in the field. Contributions to ACS Catalysis can encompass both experimental and theoretical research focused on catalytic molecules, macromolecules, and materials that exhibit catalytic turnover.