{"title":"Evidence of oxygenated species in laser-irradiated carbon particles","authors":"","doi":"10.1016/j.jaerosci.2024.106440","DOIUrl":null,"url":null,"abstract":"<div><p>Combustion-generated carbon nanoparticles exhibit a variety of optical and physicochemical properties. Therefore, when applying laser diagnostic tools for monitoring purpose, it is important to consider the different response of the particles with varying properties as well as the impact of laser irradiation on these properties. In this work, we analyze the possible modification of particle optical and physicochemical properties by coupling extinction measurements with FT-IR and Raman spectroscopy. The aim is to retrieve optical, chemical, and structural properties of the particles under analysis. To our knowledge, the approach proposed in this work has not yet been performed on irradiated particles. Particles are sampled from a premixed flame at two heights above the burner, representing two different aging stages. While extinction measurements are carried out in-flow, FT-IR and Raman spectroscopy are performed on particles collected for ex-situ analysis. Moreover, the analysis is conducted on both pristine and irradiated nanoparticles with one and ten laser shots. While nascent particles do not exhibit relevant modification under laser irradiation, heating mature particles with one or more laser pulses of relatively high energy density is observed to significantly affect absorption properties, particle structures and specific surface functionalities. The presence of oxygenated species in mature particles and in particular the structures spectroscopically correlated with graphene oxide indicates that specific chemical reaction pathways can occur under laser irradiation, likely promoted in the ambient condition under analysis.</p></div>","PeriodicalId":14880,"journal":{"name":"Journal of Aerosol Science","volume":null,"pages":null},"PeriodicalIF":3.9000,"publicationDate":"2024-08-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Aerosol Science","FirstCategoryId":"93","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0021850224001071","RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Combustion-generated carbon nanoparticles exhibit a variety of optical and physicochemical properties. Therefore, when applying laser diagnostic tools for monitoring purpose, it is important to consider the different response of the particles with varying properties as well as the impact of laser irradiation on these properties. In this work, we analyze the possible modification of particle optical and physicochemical properties by coupling extinction measurements with FT-IR and Raman spectroscopy. The aim is to retrieve optical, chemical, and structural properties of the particles under analysis. To our knowledge, the approach proposed in this work has not yet been performed on irradiated particles. Particles are sampled from a premixed flame at two heights above the burner, representing two different aging stages. While extinction measurements are carried out in-flow, FT-IR and Raman spectroscopy are performed on particles collected for ex-situ analysis. Moreover, the analysis is conducted on both pristine and irradiated nanoparticles with one and ten laser shots. While nascent particles do not exhibit relevant modification under laser irradiation, heating mature particles with one or more laser pulses of relatively high energy density is observed to significantly affect absorption properties, particle structures and specific surface functionalities. The presence of oxygenated species in mature particles and in particular the structures spectroscopically correlated with graphene oxide indicates that specific chemical reaction pathways can occur under laser irradiation, likely promoted in the ambient condition under analysis.
期刊介绍:
Founded in 1970, the Journal of Aerosol Science considers itself the prime vehicle for the publication of original work as well as reviews related to fundamental and applied aerosol research, as well as aerosol instrumentation. Its content is directed at scientists working in engineering disciplines, as well as physics, chemistry, and environmental sciences.
The editors welcome submissions of papers describing recent experimental, numerical, and theoretical research related to the following topics:
1. Fundamental Aerosol Science.
2. Applied Aerosol Science.
3. Instrumentation & Measurement Methods.