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Enhancing electrostatic spray-painting efficiency with modified high-voltage conductors: A numerical study on pulsed electric fields 改进高压导体提高静电喷涂效率:脉冲电场的数值研究
IF 3.9 3区 环境科学与生态学 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-11-24 DOI: 10.1016/j.jaerosci.2024.106491
Amine Benmoussa , Mohammad-Reza Pendar , José Carlos Páscoa
This study presents a numerical simulation of electrostatic spraying using a rotary bell sprayer equipped with a high-voltage control ring conductor. The effects of the electric field generated by constant and pulsed voltages at various frequencies applied to the electrostatic rotary bell sprayer (ERBS) with the control ring are explored. Using the OpenFOAM computational fluid dynamics framework, the simulations employ a three-dimensional Eulerian-Lagrangian method. The implemented algorithm models fully turbulent airflow using a Large Eddy Simulation (LES) approach, along with detailed modeling of spray dynamics, electric fields, and droplet tracking. The primary objective is to investigate the influence of different voltage application modes on the spraying process, with a focus on optimizing droplet consistency and control. The impacts of constant and pulsed voltages on spray plume formation, droplet volumes, and critical spraying stages are examined. Through in-depth analysis of electric field distributions, interface charge densities, and velocity fields, the complex interactions governing pulsed and constant voltage spraying processes are elucidated. The results show that pulsed voltage applied to the control ring shapes the spray plume and alters droplet behavior, though with limited effectiveness. In contrast, applying a pulsed voltage of −40 kVrms to the sprayer’s body cup at frequencies of 800 Hz and 1600 Hz significantly improves spray characteristics, resulting in a modified torus shape and a narrower size range of larger droplets compared to constant voltage condition of −40 kV. This leads to a more uniform droplet size distribution, consistent paint film, and minimal overspray. Consequently, transfer efficiency (TE) increases by 6% at 800 Hz and 4.8% at 1600 Hz compared to constant voltage. This indicates that 800 Hz is the optimal frequency for applying pulsed fields, due to its notable effectiveness in improving deposition efficiency and minimizing material waste.
本文研究了采用带有高压控制环导体的转钟式喷雾器进行静电喷涂的数值模拟。研究了恒定电压和脉冲电压在不同频率下对带控制环的静电转钟式喷雾器产生的电场影响。利用OpenFOAM计算流体动力学框架,采用三维欧拉-拉格朗日方法进行模拟。实现的算法使用大涡模拟(LES)方法对湍流气流进行全面建模,并对喷雾动力学、电场和液滴跟踪进行详细建模。主要目的是研究不同电压施加方式对喷涂过程的影响,重点是优化液滴一致性和控制。研究了恒定电压和脉冲电压对喷雾羽流形成、液滴体积和关键喷涂阶段的影响。通过对电场分布、界面电荷密度和速度场的深入分析,阐明了控制脉冲和恒压喷涂过程的复杂相互作用。结果表明,施加在控制环上的脉冲电压可以塑造喷雾羽流并改变液滴的行为,但效果有限。相比之下,在- 40 kV的恒定电压条件下,在800 Hz和1600 Hz的频率下对喷雾器的体杯施加- 40 kV的脉冲电压,可以显著改善喷雾特性,从而改善环面形状,并且与- 40 kV的恒定电压条件相比,更大液滴的尺寸范围更窄。这导致更均匀的液滴尺寸分布,一致的漆膜,和最小的过度喷涂。因此,与恒电压相比,在800hz时传输效率(TE)提高了6%,在1600hz时提高了4.8%。这表明800hz是应用脉冲场的最佳频率,因为它在提高沉积效率和减少材料浪费方面具有显著的效果。
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引用次数: 0
Deposition behavior of a CuZr metallic glass particle on amorphous-crystalline composites CuZr 金属玻璃颗粒在非晶-晶体复合材料上的沉积行为
IF 3.9 3区 环境科学与生态学 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-11-22 DOI: 10.1016/j.jaerosci.2024.106492
Nicolás Amigo
This study investigates the deposition of a CuZr metallic glass particle on amorphous/crystalline composites through molecular dynamics simulations. The research reveals that increasing impact velocities lead to greater plastic deformation and disintegration of the projectile, with noticeable differences in substrate response based on crystalline layer thickness. Thicker crystalline layers enhance the substrate’s resistance to deformation, acting as effective barriers during impact. Additionally, the interactions between the amorphous matrix and crystalline phases are critical in determining mechanical behavior. These findings provide valuable insights into the performance of coatings, particularly for cold spray applications, highlighting the importance of optimizing layer properties to improve material durability.
本研究通过分子动力学模拟研究了非晶/晶体复合材料上铜锆金属玻璃颗粒的沉积过程。研究结果表明,冲击速度的增加会导致弹丸产生更大的塑性变形和解体,晶体层厚度不同,基底的反应也有明显差异。较厚的结晶层可增强基材的抗变形能力,在撞击过程中起到有效的屏障作用。此外,无定形基体和结晶相之间的相互作用对决定机械行为至关重要。这些发现为涂层的性能,尤其是冷喷涂应用的性能提供了宝贵的见解,突出了优化涂层性能以提高材料耐久性的重要性。
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引用次数: 0
Novel quasi-static method to simulate collection efficiency and pressure drop of coalescing filters 模拟聚结过滤器收集效率和压降的新型准静态方法
IF 3.9 3区 环境科学与生态学 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-11-12 DOI: 10.1016/j.jaerosci.2024.106486
Nishant Bhatta , Sashank Gautam , Amit Kumar , Hooman V. Tafreshi , Behnam Pourdeyhimi
Coalescence filtration is the removal of dispersed droplets from a gas or from an immiscible liquid using a fibrous filter. Coalescing media are designed to capture the droplets, allow them to coalesce with one another and grow, and let them drain from the filter under gravity. Conducting numerical simulation to predict the pressure drop and collection efficiency of a coalescing filter is a computational challenge. The current paper presents a novel approach to simplify this highly transient multi-phase problem and to thereby propose a practical and expedited approach to design such filtration media. This was achieved by first developing a MATLAB code to perform Pore Morphology Method (PMM) simulations of fluid saturation in the filter and then by using the resulting 3-D saturation profiles in ANSYS (enhanced with a series of in-house subroutines) to conduct aerosol filtration simulations. Our simulations, interestingly, revealed that collection efficiency of a coalescing filter can decrease with increasing fluid saturation in the media, while its pressure drop can only increase. Our simulation results are analyzed in detail and are discussed in the context of prior studies reported in the literature.
聚结过滤是使用纤维过滤器从气体或不相溶的液体中去除分散的液滴。聚结介质的设计目的是捕获液滴,使其相互聚结并增长,然后在重力作用下从过滤器中排出。进行数值模拟以预测凝聚过滤器的压降和收集效率是一项计算挑战。本文提出了一种新方法来简化这一高度瞬态的多相问题,从而为设计此类过滤介质提出了一种切实可行的快速方法。为此,我们首先开发了一套 MATLAB 代码,用于对过滤器中的流体饱和度进行孔形态法 (PMM) 模拟,然后在 ANSYS(使用一系列内部子程序进行了增强)中使用生成的三维饱和度剖面图进行气溶胶过滤模拟。有趣的是,我们的模拟结果表明,聚结过滤器的收集效率会随着介质中流体饱和度的增加而降低,而压降只会增加。我们对模拟结果进行了详细分析,并结合先前的文献研究进行了讨论。
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引用次数: 0
Dry powder inhaler deposition in the larynx and the risk of steroid inhaler laryngitis: A computational fluid dynamics study 干粉吸入器在喉部的沉积与类固醇吸入器喉炎的风险:计算流体动力学研究
IF 3.9 3区 环境科学与生态学 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-11-12 DOI: 10.1016/j.jaerosci.2024.106490
Shamudra Dey , Jonathan M. Bock , Guilherme J.M. Garcia
Dry Powder Inhalers (DPIs) are a mainstay in the treatment of obstructive respiratory diseases, including asthma and chronic obstructive pulmonary disease (COPD). Deposition of inhaled corticosteroids in the larynx elicits local side effects, potentially leading to steroid inhaler laryngitis. The objective of this study was to estimate the dose of DPIs that are deposited in the larynx relative to other regions of the respiratory tract using computational fluid dynamics (CFD). An anatomically accurate model of the airways (mouth to main bronchi) was constructed based on medical imaging of a healthy adult. Respiratory airflow and particle transport were simulated for constant inhalation rates of 30, 45, and 60 L/min. Two turbulence models were compared, namely the large eddy simulation (LES) and the kωSST models. DPIs were assumed to generate an aerosol cloud with a log-normal particle size distribution characterized by the mass median aerodynamic diameter (d50) and geometric standard deviation (σg). We compared two commercial DPIs, namely DPI 1 had a large particle size (d50 = 50 μm, σg=2.55) and DPI 2 had a small particle size (d50 = 2 μm, σg=1.99). The laryngeal dose was 1.6-to-3.8-fold higher than the bronchial dose for DPI 1, while the laryngeal and bronchial doses (units of mass per unit surface area) were similar for DPI 2 for both turbulence models and all inhalation rates. The choice of turbulence model had little impact on the total extrathoracic deposition, but a significant impact on regional doses, with the LES model predicting higher larynx-to-bronchi relative doses than the kω model. Our prediction that the larynx is a hotspot for DPI deposition is consistent with the observation of laryngeal side effects in DPI users. Importantly, our simulations suggest that DPIs with larger particles (d50 = 50 μm) may increase the risk of steroid inhaler laryngitis.
干粉吸入器(DPI)是治疗哮喘和慢性阻塞性肺病(COPD)等阻塞性呼吸道疾病的主要药物。吸入的皮质类固醇沉积在喉部会产生局部副作用,可能导致类固醇吸入器性喉炎。本研究的目的是利用计算流体动力学(CFD)估算相对于呼吸道其他区域沉积在喉部的 DPIs 剂量。根据健康成年人的医学影像,构建了一个解剖精确的呼吸道(从口腔到主支气管)模型。模拟了 30、45 和 60 升/分钟恒定吸入速率下的呼吸气流和颗粒传输。比较了两种湍流模型,即大涡流模拟(LES)和 k-ωSST 模型。假定 DPI 生成的气溶胶云具有对数正态粒度分布,其特征是质量中值空气动力学直径(d50)和几何标准偏差(σg)。我们比较了两种商用干粉吸入器,即粒径较大的干粉吸入器 1(d50 = 50 μm,σg=2.55)和粒径较小的干粉吸入器 2(d50 = 2 μm,σg=1.99)。DPI 1 的喉部剂量是支气管剂量的 1.6-3.8 倍,而 DPI 2 在两种湍流模型和所有吸入速率下的喉部和支气管剂量(单位表面积质量)相似。湍流模型的选择对胸腔外总沉积量的影响很小,但对区域剂量的影响很大,LES 模型预测的喉-支气管相对剂量高于 k-ω 模型。我们预测喉部是 DPI 沉积的热点,这与观察到的 DPI 使用者喉部副作用是一致的。重要的是,我们的模拟结果表明,颗粒较大(d50 = 50 μm)的干粉吸入器可能会增加类固醇吸入器喉炎的风险。
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引用次数: 0
Dust resuspension from contaminated fabrics subjected to force-induced vibrations 受力振动污染织物的粉尘再悬浮
IF 3.9 3区 环境科学与生态学 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-11-12 DOI: 10.1016/j.jaerosci.2024.106489
Jie Feng , Ka Chung Chan , Chun-Ho Liu , Christopher Y.H. Chao , Sau Chung Fu
A parametric study inspired by daily human activities (e.g., shaking clothes) is presented in this paper. Dust resuspension from contaminated fabrics (with four levels of initial dust load: 1, 10, 20, and 30 g/m2) subjected to force-induced vibrations (with low frequencies ranging from 0 to 6 Hz) was experimentally investigated. It was found that different settings of vibration duration, vibration frequency, and initial dust load can lead to significant differences in the resuspension results. Flexible fabric motion and multilayer dust motion were demonstrated as major contributors through visualization experiments. The observed phenomena of acceleration amplification effect along the fabric and various particle-particle interactions provided a crucial basis for our reasonable assumptions in the mathematical description. A set of empirical correlations was therefore developed whose form was proposed to be applicable in a wide range of scenarios involving moving surfaces. This paper not only reveals an everyday event that can trigger particulate matter emissions, but also helps enrich the understanding of particle dynamics.
本文介绍了受人类日常活动(如抖动衣服)启发而进行的参数研究。实验研究了受污染织物(初始粉尘负荷为 1、10、20 和 30 g/m2 四种水平)在力诱导振动(0 至 6 Hz 的低频)作用下的粉尘再悬浮情况。结果发现,不同的振动持续时间、振动频率和初始灰尘载荷设置会导致再悬浮结果的显著差异。通过可视化实验证明,柔性织物运动和多层粉尘运动是主要原因。沿织物观察到的加速度放大效应和各种粒子间的相互作用现象为我们在数学描述中进行合理假设提供了重要依据。因此,我们开发了一套经验相关性,其形式适用于涉及运动表面的各种情况。本文不仅揭示了可能引发颗粒物排放的日常事件,还有助于丰富对颗粒物动力学的理解。
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引用次数: 0
Numerical simulation and experimental analysis of aerosol deposition: Investigating nozzle effects on particle dynamics and deposition 气溶胶沉积的数值模拟和实验分析:研究喷嘴对粒子动力学和沉积的影响
IF 3.9 3区 环境科学与生态学 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-11-07 DOI: 10.1016/j.jaerosci.2024.106488
Mahendhar Kumar Kumar , Zhenying Yang , Mehdi Jadidi , Thomas W. Coyle , Ali Dolatabadi
Aerosol deposition (AD), also known as vacuum kinetic spray (VKS), is used to deposit dense ceramic films onto a substrate surface at room temperature. One predominant factor influencing the overall deposition process is the nozzle geometry, which significantly impacts the quality, shape, and thickness of the coating. To evaluate the effect of nozzle geometry in AD, particle trajectory and impact velocity were investigated via computational simulation. A Eulerian-Lagrangian model was used to simulate the gas flow, particle in-flight behavior, as well as particle deposition characteristics on a flat substrate. Three common nozzle geometries in AD were utilized: a converging-diverging nozzle with a slit cross-section (CD-Slit), a converging-barrel nozzle with a slit cross-section (CB-Slit), and a converging-diverging round (CD-Round) nozzle. Moreover, suitable drag coefficient and Nusselt number correlations were used to account for compressibility and rarefaction effects on particle dynamics and heat transfer. The simulation results were compared to the deposition pattern obtained experimentally. The results demonstrate that shape of the nozzle has profound effect on the particle impact velocity and deposition pattern. The CD-Round nozzle provides uniform, thinner coatings ideal for extensive surfaces at a slower deposition rate. In contrast, the CB-Slit nozzle is optimized for maximum coating thickness in narrow, thick linear patterns. The CD-Slit nozzle achieves high deposition rates with uniform coatings and a distinctive cat-ear shaped pattern.
气溶胶沉积(AD)又称真空动力学喷雾(VKS),用于在室温下在基底表面沉积致密的陶瓷膜。影响整个沉积过程的一个主要因素是喷嘴的几何形状,它对涂层的质量、形状和厚度有很大影响。为了评估喷嘴几何形状在 AD 中的影响,我们通过计算模拟研究了粒子轨迹和冲击速度。我们使用欧拉-拉格朗日模型模拟了气体流动、粒子飞行过程以及粒子在平面基底上的沉积特性。模拟采用了 AD 中三种常见的喷嘴几何形状:具有狭缝截面的会聚-发散喷嘴(CD-Slit)、具有狭缝截面的会聚-桶形喷嘴(CB-Slit)和会聚-发散圆形喷嘴(CD-Round)。此外,还使用了适当的阻力系数和努塞尔特数相关系数,以考虑颗粒动力学和热传递的可压缩性和稀释效应。模拟结果与实验获得的沉积模式进行了比较。结果表明,喷嘴的形状对粒子撞击速度和沉积模式有深远影响。CD-Round 喷嘴能以较慢的沉积速度为大面积表面提供均匀、较薄的涂层。相比之下,CB-Slit 喷嘴经过优化,可在窄而厚的线性图案中实现最大涂层厚度。CD-Slit 喷嘴的沉积速率高,涂层均匀,图案呈独特的猫耳形。
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引用次数: 0
Influencing factors analysis of infectious SARS-CoV-2 aerosols sampling 传染性 SARS-CoV-2 气溶胶采样的影响因素分析
IF 3.9 3区 环境科学与生态学 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-11-05 DOI: 10.1016/j.jaerosci.2024.106487
Yunfeng Chen , Jia Lu , Qingni Li , Wanlu Hua , Wenjin Zhang , Chunyang Li , Yuanlang Liu , Zejun Wang
Assessing the potential infectivity of airborne viruses is critical for evaluating the risk of their transmission through air. This study investigated the factors influencing the collection of infectious SARS-CoV-2 aerosols using three common aerosol samplers: the impactor sampler AGI-30, the SKC Biosampler, and a cyclone sampler WA-400III. It was found that the sampling process over time significantly impacted the infectivity of SARS-CoV-2 captured in the sampler, and the infectivity loss of different SARS-CoV-2 variants in the process varied. Additionally, adding newborn calf serum in the collection suspension could effectively preserve viral infectivity in the sampler. Further tests conducted under various ventilation occasions indicated that ventilation can reduce the virus concentration in the environment and rapidly clear viral particles after aerosol generation. Although the flow rate of WA-400III is higher, it only could collect higher concentrations of viral RNA instead of live viruses than AGI-30 or SKC Biosampler when aerosol was generated constantly in the environment. After aerosol generation stopped, the WA-400III collected more infectious viruses and viral RNA. This study highlights the impact of the sampling process on captured virus should be assessed and protective agent is needed to preserve viral viability. And it is crucial to select appropriate sampler based on environmental characteristics and research objectives for obtaining optimal results. The AGI-30 and SKC Biosampler are preferable for collecting infectious viruses in environments with high aerosol concentrations, while the cyclone sampler WA-400III is more effective for collecting viral nucleic acids and enriching virus samples in confined spaces with lower viral loads.
评估空气传播病毒的潜在感染性对于评估病毒通过空气传播的风险至关重要。本研究使用三种常见的气溶胶采样器:AGI-30 冲击采样器、SKC 生物采样器和 WA-400III 旋风采样器,调查了影响采集传染性 SARS-CoV-2 气溶胶的因素。研究发现,随着时间的推移,采样过程会对采样器捕获的 SARS-CoV-2 的感染性产生重大影响,不同 SARS-CoV-2 变体在采样过程中的感染性损失也各不相同。此外,在采集悬浮液中加入新生小牛血清可有效保持采样器中病毒的感染性。在不同通风条件下进行的进一步测试表明,通风可以降低环境中的病毒浓度,并在产生气溶胶后迅速清除病毒颗粒。虽然 WA-400III 的流速较高,但与 AGI-30 或 SKC 生物采样器相比,当环境中不断产生气溶胶时,WA-400III 只能采集到更高浓度的病毒 RNA 而不是活病毒。气溶胶停止产生后,WA-400III 收集到的传染性病毒和病毒 RNA 更多。这项研究强调,应评估采样过程对捕获病毒的影响,并需要保护剂来保持病毒的活力。根据环境特征和研究目标选择合适的采样器对获得最佳结果至关重要。AGI-30 和 SKC 生物采样器适用于在气溶胶浓度较高的环境中采集传染性病毒,而旋风式采样器 WA-400III 则更适用于在病毒负荷较低的密闭空间中采集病毒核酸和富集病毒样本。
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引用次数: 0
Non-linear optics for an online probing of the specific surface area of nanoparticles in the aerosol phase 在线探测气溶胶相中纳米颗粒比表面积的非线性光学技术
IF 3.9 3区 环境科学与生态学 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-11-02 DOI: 10.1016/j.jaerosci.2024.106484
M. Joret, S. Idlahcen, M. Mazur, J. Yon
In the present study the generation of non-linear optical (NLO) effects, such as second harmonic generation (SHG), by black carbon particles, also named soot, and by other types of nanoparticles in aerosol phase is quantified and analysed. Its potential for measuring the specific surface area of an aerosol is put forward. SHG is a Non Linear Optical phenomenon that is typically used in biosciences and fundamental physics and has shown to have large potential for the investigation of surface sensitive phenomena. It exists in two forms, coherent SHG and incoherent SHG, also named Hyper Rayleigh Scattering (HRS). While applications on particles in solution or organic molecules located on the surface of droplets exist, the SHG naturally induced by solid nanoparticles in aerosol phase without any SHG enhancing additive has neither been detected nor quantified yet. The present work aims at narrowing this gap by exposing a jet of well-characterized nanoaerosols to a femtosecond laser featuring high peak pulse energies allowing to induce NLO phenomena. The experiments are carried out in an innovative optical setup allowing to analyse the NLO response resolved in time, wavelength and angle, thus having the capability to isolate SHG from other phenomena, such as laser filamentation. The optical setup was calibrated in order to quantify the generated signal power and optimized in order to have a high sensitivity and in order to avoid NLO generation from its own optical elements. The results confirm that soot particles, as well as DEHS droplets and arc generated carbon nanoparticles, feature SHG at intensities that are more than 7 orders of magnitude smaller than that of static light scattering. SHG depends in particular on aggregate and/or monomer size. On the other hand, SHG induced by soot does not seem to depend on the organic or elementary carbon content. The experiments also show that the detected NLO signal increases linearly with particle surface area, independently of the particle shape or composition. Finally, the angular response of NLO signal is fundamentally different from that of linear scattering. Due to the isotropic nature of the angular response, the observed SHG signal is probably non-coherent and thus related to Hyper Raleigh Scattering. These findings show the potential of non-linear optics, in particular to quantify in situ the specific surface of an aerosol. Giving access to this information which is crucial in the evaluation of toxicity of aerosols, the present work can thus give way to a new class of laser based diagnostics for aerosols.
本研究对气溶胶相中黑碳颗粒(也称为烟尘)和其他类型的纳米颗粒产生的非线性光学(NLO)效应(如二次谐波发生(SHG))进行了量化和分析。并提出了它在测量气溶胶比表面积方面的潜力。SHG 是一种非线性光学现象,通常用于生物科学和基础物理学,在研究表面敏感现象方面具有很大的潜力。它有两种形式:相干 SHG 和非相干 SHG,也称为超瑞利散射(HRS)。虽然在溶液中的颗粒或位于液滴表面的有机分子上已有应用,但在没有任何 SHG 增强添加剂的情况下,气溶胶相中的固体纳米颗粒自然诱发的 SHG 尚未被检测或量化。本研究旨在缩小这一差距,方法是将特性良好的纳米气溶胶喷射暴露在具有高峰值脉冲能量的飞秒激光下,从而诱发 NLO 现象。实验是在一种创新的光学装置中进行的,该装置可以分析在时间、波长和角度上分辨的 NLO 响应,从而能够将 SHG 与激光丝化等其他现象隔离开来。为了量化产生的信号功率,对光学装置进行了校准,并对其进行了优化,以获得高灵敏度,避免其自身光学元件产生 NLO。结果证实,烟尘颗粒、DEHS 液滴和电弧产生的碳纳米颗粒都具有 SHG 特性,其强度比静态光散射小 7 个数量级以上。SHG 尤其取决于聚合体和/或单体的大小。另一方面,烟尘诱导的 SHG 似乎与有机碳或基本碳的含量无关。实验还表明,检测到的 NLO 信号随颗粒表面积的增加而线性增加,与颗粒形状或成分无关。最后,NLO 信号的角度响应与线性散射有着本质区别。由于角度响应的各向同性,观测到的 SHG 信号可能是非相干的,因此与超雷利散射有关。这些发现显示了非线性光学的潜力,特别是对气溶胶比表面进行现场量化的潜力。这些信息对于评估气溶胶的毒性至关重要,因此,本研究成果可以为基于激光的新型气溶胶诊断技术开辟道路。
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引用次数: 0
Potential human exposure and risks of incidental nanoparticles released during rotary dry cutting of ceramic tiles 瓷砖旋转干切过程中附带释放的纳米颗粒对人体的潜在暴露和风险
IF 3.9 3区 环境科学与生态学 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-11-02 DOI: 10.1016/j.jaerosci.2024.106485
Verónica Moreno-Martín , Maria López , Cristian Roldan , David Bou , Sonia Fraga , João Paulo Teixeira , Ana López-Lilao , Vicenta Sanfélix , Raúl Moliner , Eliseo Monfort , Mar Viana
Rotary dry cutting and rectifying of ceramic tiles are sources of fine particulate matter (PM2.5) and nanoparticles (NPs). These activities are typically carried out inside industrial facilities during the manufacturing process, as well as outdoors and in residential indoor spaces during the installation phase, where mitigation measures are seldom implemented. This work aimed to understand the particle formation and release mechanisms, as well as particle properties (physical, chemical, and toxicological) and potential impacts on human health and the environment, for particles generated during ceramic tile rotary dry cutting operations. Aerosols were characterised in terms of particle number and mass concentrations, chemical composition, morphology and in vitro cytotoxicity. Two types of commercially available and representative tiles were tested in controlled chamber experiments: porous and non-porous ceramic body tiles (referred to in this work as A and B types, respectively). Results evidenced the release of fine particles and NPs during dry cutting of both materials, in comparable concentrations (20.000–45.000/cm3, 1-min average). However, the particle size distribution was significantly finer from A tiles (70% of the particle number concentration was nanosized (<100 nm)) in comparison to B tiles (<20%). While airborne particle chemical profiles were similar for both types of materials in the coarser size fractions (>0.6 μm), in the smaller size fractions (<0.6 μm) larger differences were observed. The chemical composition of airborne aerosols was consistent with that of the deposited dust. In vitro cytotoxicity responses evidenced statistically significant differences between exposure to aerosols from both types of tiles: cell viability was lower after exposure to aerosols from A tiles (50% at the original concentration) compared to those from B tiles, which exhibited high cell viability regardless of the aerosol concentration. Overall, results evidenced NP formation and release during rotary dry cutting of ceramic tiles, varying physical-chemical and cytotoxic profiles as a function of the material being processed, and highlight this activity as a potential health hazard in scenarios where prevention and mitigation measures are not implemented.
瓷砖的旋转干切和整平是细颗粒物(PM2.5)和纳米颗粒物(NPs)的来源。这些活动通常在生产过程中在工业设施内进行,以及在安装阶段在室外和住宅室内空间进行,很少采取缓解措施。这项工作旨在了解瓷砖旋转干切割操作过程中产生的颗粒的形成和释放机制、颗粒特性(物理、化学和毒理学)以及对人类健康和环境的潜在影响。气溶胶的特征包括颗粒数量和质量浓度、化学成分、形态和体外细胞毒性。在控制室实验中测试了两种市售的具有代表性的瓷砖:多孔和无孔陶瓷砖(在本文中分别称为 A 型和 B 型)。结果表明,两种材料在干切过程中都释放出了细颗粒和 NPs,浓度相当(20.000-45.000/立方厘米,1 分钟平均值)。不过,与 B 型瓷砖(20%)相比,A 型瓷砖的粒度分布明显更细(70% 的颗粒数浓度为纳米级(100 纳米))。虽然两类材料在较粗粒径部分(0.6 微米)的空气传播颗粒化学成分情况相似,但在较小粒径部分(0.6 微米)却观察到了较大的差异。气载气溶胶的化学成分与沉积粉尘的化学成分一致。体外细胞毒性反应表明,暴露于两种类型瓷砖产生的气溶胶之间存在显著的统计学差异:暴露于 A 型瓷砖产生的气溶胶(原始浓度为 50%)后,细胞存活率低于暴露于 B 型瓷砖产生的气溶胶后,无论气溶胶浓度如何,细胞存活率都很高。总之,研究结果表明,在瓷砖旋转干切过程中会形成和释放 NP,不同的加工材料会产生不同的物理化学和细胞毒性特征,并强调在不采取预防和缓解措施的情况下,这种活动会对健康造成潜在危害。
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引用次数: 0
Aerosol physical characterization: A review on the current state of aerosol documentary standards and calibration strategies 气溶胶物理特征描述:气溶胶文献标准和校准策略现状综述
IF 3.9 3区 环境科学与生态学 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-10-30 DOI: 10.1016/j.jaerosci.2024.106483
Konstantina Vasilatou , Kenjiro Iida , Mohsen Kazemimanesh , Jason Olfert , Hiromu Sakurai , Timothy A. Sipkens , Gregory J. Smallwood
Aerosols have a wide-ranging impact on the climate, air quality, human health, and agriculture. Despite the ongoing advances in aerosol measurement science and technology, the uncertainties in quantifying aerosol physical properties remain significant in many applications. The accurate characterization of airborne particles - including number and mass concentration, size distribution and light absorption - is critical for understanding their behavior in the atmosphere and environmental fate. We delve into the physical characterization of aerosols, highlighting the measurement and documentary standards that underpin measurement traceability and enable comparison of data collected by instruments based on measurement principles at different times or locations. In particle metrology, recent advances have led to sophisticated primary measurement standards, with relative expanded measurement uncertainties down to 1.1 % (coverage factor k = 2; 95 % confidence interval). These standards enable time- and cost-effective instrument calibration to support research, industry, and legislation. We discuss documentary standards and regulations related to air quality and control of particle emissions from vehicles, aviation, shipping, and stationary sources, with the aim to increase awareness of these documents and underline differences in measurement protocols in different sub-fields of aerosol sciences. Importantly, we emphasize the need for further harmonization of measurement procedures, providing specific examples and making suggestions towards this goal. This review, with its comprehensive coverage of aerosol measurement and documentary standards across different sub-disciplines, can serve as a reliable guide for scientists and regulators interested in improving the accuracy of their measurements.
气溶胶对气候、空气质量、人类健康和农业有着广泛的影响。尽管气溶胶测量科学和技术不断进步,但在许多应用中,气溶胶物理特性量化的不确定性仍然很大。准确描述气载粒子的特性(包括数量和质量浓度、粒度分布和光吸收)对于了解它们在大气中的行为和环境归宿至关重要。我们将深入探讨气溶胶的物理特性,重点介绍测量和文件标准,这些标准是测量可追溯性的基础,可以对不同时间或地点基于测量原理的仪器所收集的数据进行比较。在粒子计量学方面,最近的进步带来了先进的初级测量标准,相对扩大的测量不确定性可低至 1.1%(覆盖因子 k = 2;置信区间 95%)。通过这些标准,可以对仪器进行及时、经济的校准,从而为研究、工业和立法提供支持。我们讨论了与空气质量以及车辆、航空、航运和固定污染源颗粒物排放控制有关的文件标准和法规,旨在提高对这些文件的认识,并强调气溶胶科学不同子领域测量协议的差异。重要的是,我们强调了进一步统一测量程序的必要性,提供了具体的例子,并为实现这一目标提出了建议。本综述全面涵盖了不同子学科的气溶胶测量和文件标准,可作为有志于提高测量精度的科学家和监管人员的可靠指南。
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引用次数: 0
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Journal of Aerosol Science
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