Green Synthesis of Lactirofoam Using the Micronization Process

IF 2.2 4区 工程技术 Q1 MATERIALS SCIENCE, TEXTILES Fibers and Polymers Pub Date : 2024-08-05 DOI:10.1007/s12221-024-00656-8
Iman Mohammadi Dehcheshmeh, Marco Frediani, Ahmad Poursattar Marjani, Peyman Najafi Moghadam
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Abstract

In particular, foams have been given a lot of attention in the packaging industry and other sectors over the years. In this study, low-density white lactirofoam is created using micronized polylactide particles, and the essence of making it environmentally friendly is considered. A new approach covering four key stages was used in the synthesis of lactirofoam, involving a ring-opening polymerization process for L-lactide, emulsion micronization solution preparation, deposition, and molding. Characterization by ATR-IR and 1H-NMR techniques confirmed the synthesis of the polylactide polymer. The optical micrograph showed that the process of micronization of the lactirofoam particles was quite efficient. The GPC analysis confirmed that the key to controlling the molecular weight of the final polymer during ROP in order to achieve the desired density of lactirofoams was a specific choice of molar ratios for starting monomers. In addition, lactirofoam’s temperature properties have been determined using TG/DTG/DTA. With the molecular weight of the polymer, they confirmed an increase in the thermal stability of lactirofoam.

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利用微粉化工艺绿色合成乳脂泡沫
尤其是泡沫塑料,多年来在包装行业和其他领域受到广泛关注。在这项研究中,使用微粉化聚乳酸颗粒制造了低密度白色乳脂泡沫,并探讨了使其成为环保型泡沫的本质。在合成乳脂泡沫的过程中,采用了一种涵盖四个关键阶段的新方法,包括 L-内酰胺开环聚合工艺、乳液微粉化溶液制备、沉积和成型。ATR-IR 和 1H-NMR 技术的表征证实了聚乳酸聚合物的合成。光学显微照片显示,乳脂泡沫颗粒的微粉化过程相当有效。GPC 分析证实,要在 ROP 过程中控制最终聚合物的分子量,以达到理想的乳泡沫密度,关键在于对起始单体摩尔比的特定选择。此外,还使用 TG/DTG/DTA 测定了乳泡沫的温度特性。结果表明,随着聚合物分子量的增加,乳泡沫的热稳定性也随之增加。
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来源期刊
Fibers and Polymers
Fibers and Polymers 工程技术-材料科学:纺织
CiteScore
3.90
自引率
8.00%
发文量
267
审稿时长
3.9 months
期刊介绍: -Chemistry of Fiber Materials, Polymer Reactions and Synthesis- Physical Properties of Fibers, Polymer Blends and Composites- Fiber Spinning and Textile Processing, Polymer Physics, Morphology- Colorants and Dyeing, Polymer Analysis and Characterization- Chemical Aftertreatment of Textiles, Polymer Processing and Rheology- Textile and Apparel Science, Functional Polymers
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