Effect of alkaline solution on hydraulic and mechanical properties of MX80 granular bentonite

IF 1.9 3区 工程技术 Q1 NUCLEAR SCIENCE & TECHNOLOGY Annals of Nuclear Energy Pub Date : 2024-08-08 DOI:10.1016/j.anucene.2024.110822
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Abstract

Granular bentonite is commonly regarded as a preferred anti-seepage and plugging material for the joints in high-level radioactive waste (HLW) repository. This study investigated the swelling, compression, rebound and permeability properties of MX80 granular bentonite with alkaline solution (0–1.0 mol/L). Results showed that compared with the alkaline concentration, the final swelling strain, compression and rebound indexes were negligibly affected by the particle size distribution. The preconsolidation pressure and hydraulic conductivity increased with increasing the concentration. When concentration c < 0.3 mol/L, the hydraulic conductivity was less affected by alkaline solution. When c > 0.3 mol/L, large aggregates were dissolved and resulted in a higher hydraulic conductivity. Results of scanning electron microscope (SEM) and processed images showed that the complexity, roughness and the size of the pores increased as the concentration increased. The dissolution of montmorillonite affected the pore size distribution and the hydraulic and mechanical properties of granular bentonite.

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碱性溶液对 MX80 粒状膨润土水力和机械特性的影响
颗粒膨润土通常被认为是高放射性废物(HLW)储存库接缝处的首选防渗和堵塞材料。本研究考察了 MX80 颗粒膨润土在碱性溶液(0-1.0 mol/L)中的膨胀、压缩、回弹和渗透特性。结果表明,与碱性浓度相比,粒度分布对最终膨胀应变、压缩和回弹指数的影响微乎其微。预固结压力和水导率随浓度的增加而增加。当浓度小于 0.3 mol/L 时,水导率受碱性溶液的影响较小。当浓度为 0.3 mol/L 时,大颗粒聚集体被溶解,导致水导率升高。扫描电子显微镜(SEM)和处理图像的结果表明,孔隙的复杂性、粗糙度和大小随着浓度的增加而增加。蒙脱石的溶解影响了颗粒膨润土的孔径分布以及水力和机械性能。
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来源期刊
Annals of Nuclear Energy
Annals of Nuclear Energy 工程技术-核科学技术
CiteScore
4.30
自引率
21.10%
发文量
632
审稿时长
7.3 months
期刊介绍: Annals of Nuclear Energy provides an international medium for the communication of original research, ideas and developments in all areas of the field of nuclear energy science and technology. Its scope embraces nuclear fuel reserves, fuel cycles and cost, materials, processing, system and component technology (fission only), design and optimization, direct conversion of nuclear energy sources, environmental control, reactor physics, heat transfer and fluid dynamics, structural analysis, fuel management, future developments, nuclear fuel and safety, nuclear aerosol, neutron physics, computer technology (both software and hardware), risk assessment, radioactive waste disposal and reactor thermal hydraulics. Papers submitted to Annals need to demonstrate a clear link to nuclear power generation/nuclear engineering. Papers which deal with pure nuclear physics, pure health physics, imaging, or attenuation and shielding properties of concretes and various geological materials are not within the scope of the journal. Also, papers that deal with policy or economics are not within the scope of the journal.
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