Evolution of macromolecular structure during coal oxidation via FTIR, XRD and Raman

Abstract

The analysis of the macromolecular structure and morphology in coal during oxidation is the basis to explore the mechanism of spontaneous combustion. To explore the evolutionary rules of coal macromolecular structure during oxidation, Fourier Transform Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD), and Raman Spectroscopy (Raman) were employed to analyze the coal samples with different oxidation degrees. The results revealed that the oxidation action led to the decrease of the aliphatic structures and aromatic hydroxyl groups in coal, while promoting the formation of oxygen-containing functional groups and aromatic structures. It also led to a relative increase of free hydroxyl groups linked to hydrogen bonds. The aromatic layer spacing (d₀₀₂) decreased with increasing oxidation degree, while the microcrystal stacking height (L_c), the aromatic layer diameter (L_a), the average number of crystal stacking layers (n) generally increased. It indicated that small aromatic ring molecules in coal could undergo continuous polymerization during oxidation to form a single aromatic layer structure. The variation of Raman spectrum parameters exhibited a consistent decreasing trend in W_D/W_G, I_D/I_G, A_D/A_G, and A_(GR+SL)/A_G value, indicating an increase in the vibration of sp² hybridization carbon atoms within the lattice structure of coal. Conversely, P_G-D, A_S/A_D and A_(GR+VL+VR)/A_D value increased overall, suggesting that small aromatic rings decreased in content during oxidation while polymerizing into larger aromatic rings. The coal structure underwent a brief stage of disordered evolution during oxidation, followed by removal of impurity structures and condensation of aromatic structures due to increasing oxidation temperatures, ultimately leading to a highly ordered crystalline state. The oxidation process significantly influenced the development of coal's aromatic structure, particularly in less metamorphic coal. The research findings provide a theoretical basis for analyzing the underlying mechanism behind spontaneous combustion induced by coal oxidation.