Oxidation Behavior of MgO‐C Refractories Containing Metallic Aluminum, Calcium Magnesium Aluminate Aggregates, and Carbores P

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-08-04 DOI:10.1002/srin.202400260
Anton Yehorov, Xingwen Wei, Sofia Mazepa, Anastasiia Sherstneva, Olena Volkova
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Abstract

The current investigation delves into the oxidation resistance of magnesia‐carbon‐bonded (MgO‐C) refractory enhanced with calcium magnesium aluminate (CMA) cement, metallic aluminum, and Carbores P across a broad temperature spectrum from 800 to 1600 °C. The results demonstrate that the modification with CMA up to a temperature threshold of 1200 °C does not compromise the material's inherent oxidation resistance. However, above this temperature, a decrement in oxidation resistance is observed. The impact of grain size variation in CMA on the oxidation resistance of MgO‐C refractories is notable, and the finer grains show a superior performance. MgO‐C sample with Carbores P has excellent oxidation resistance up to 1000 °C, while above 1200 °C, its oxidation resistance strongly deteriorates. The metallic aluminum addition exhibits a remarkable oxidation resistance throughout the evaluated temperature range, indicated by a slight oxidation.
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含金属铝、铝酸钙镁骨料和碳酸钙的氧化镁-C 耐火材料的氧化行为 P
目前的研究深入探讨了使用钙镁铝酸盐(CMA)水泥、金属铝和 Carbores P 增强的氧化镁-碳键(MgO-C)耐火材料在 800 至 1600 ℃ 宽温度范围内的抗氧化性。结果表明,在 1200 °C 的温度临界值之前,使用 CMA 进行改性不会影响材料固有的抗氧化性。然而,超过这一温度后,抗氧化性就会下降。CMA 中晶粒大小的变化对氧化镁-C 耐火材料抗氧化性的影响非常明显,较细的晶粒表现出更优越的性能。含有 Carbores P 的氧化镁-C 样品在 1000 ℃ 以下具有极佳的抗氧化性,而在 1200 ℃ 以上,其抗氧化性则严重下降。添加了金属铝的样品在整个评估温度范围内都表现出显著的抗氧化性,表现为轻微氧化。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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