Selection of Negative Charged Acidic Polar Additives to Regulate Electric Double Layer for Stable Zinc Ion Battery

IF 26.6 1区 材料科学 Q1 Engineering Nano-Micro Letters Pub Date : 2024-08-14 DOI:10.1007/s40820-024-01475-5
Xing Fan, Lina Chen, Yongjing Wang, Xieyu Xu, Xingxing Jiao, Peng Zhou, Yangyang Liu, Zhongxiao Song, Jiang Zhou
{"title":"Selection of Negative Charged Acidic Polar Additives to Regulate Electric Double Layer for Stable Zinc Ion Battery","authors":"Xing Fan,&nbsp;Lina Chen,&nbsp;Yongjing Wang,&nbsp;Xieyu Xu,&nbsp;Xingxing Jiao,&nbsp;Peng Zhou,&nbsp;Yangyang Liu,&nbsp;Zhongxiao Song,&nbsp;Jiang Zhou","doi":"10.1007/s40820-024-01475-5","DOIUrl":null,"url":null,"abstract":"<div><h2>Highlights</h2><div>\n \n <ul>\n <li>\n <p>Negative charged acidic polarity (NCAP) has been unveiled as the guideline for selecting additives to regulate electric double layer (EDL) for Zn-ion batteries.</p>\n </li>\n <li>\n <p>NCAP glutamate has been verified to regulate EDL structure with synergetic effects, including preferential adsorption on Zn anode and reconstruction of hydrated Zn-ion clusters.</p>\n </li>\n <li>\n <p>Adding NCAP additives, Zn|Cu half-cell achieves a high Coulombic efficiency of 99.83% for 2000 cycles, and NH<sub>4</sub>V<sub>4</sub>O<sub>10</sub>|Zn full cell realizes a high-capacity retention of 82.1% for 3000 cycles.</p>\n </li>\n </ul>\n </div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"16 1","pages":""},"PeriodicalIF":26.6000,"publicationDate":"2024-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11324644/pdf/","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nano-Micro Letters","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s40820-024-01475-5","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Engineering","Score":null,"Total":0}
引用次数: 0

Abstract

Highlights

  • Negative charged acidic polarity (NCAP) has been unveiled as the guideline for selecting additives to regulate electric double layer (EDL) for Zn-ion batteries.

  • NCAP glutamate has been verified to regulate EDL structure with synergetic effects, including preferential adsorption on Zn anode and reconstruction of hydrated Zn-ion clusters.

  • Adding NCAP additives, Zn|Cu half-cell achieves a high Coulombic efficiency of 99.83% for 2000 cycles, and NH4V4O10|Zn full cell realizes a high-capacity retention of 82.1% for 3000 cycles.

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
选择带负电荷的酸性极性添加剂来调节稳定锌离子电池的双电层。
锌离子电池在大规模电化学储能系统中大有可为,但仍存在界面问题,例如氢演化副反应(HER)、自腐蚀和不可控制的树枝状锌电沉积。虽然电双电层(EDL)的调节作用已在界面问题上得到验证,但选择添加剂作为调节剂的原理仍是迷雾重重。在此,我们研究了几种具有不同特性的典型氨基酸,以揭示在锌阳极上调节双电层的界面行为。带负电荷的酸性极性(NCAP)已被揭示为选择添加剂的准则,以重建具有内部亲锌 H2O 贫层的 EDL,并用 NCAP 谷氨酸取代水合 Zn2+ 的 H2O 分子。利用 EDL 调节的协同效应,通过抑制 HER 和抗自腐蚀的均匀电沉积,可显著稳定不可控界面。因此,通过添加 NCAP 谷氨酸钠,Zn|Cu 不对称电池在超过 2000 次循环后,Zn 金属的平均库仑效率高达 99.83%,而 NH4V4O10|Zn 全电池在 2 A g-1 条件下循环 3000 次后,显示出 82.1% 的高容量保持率。综上所述,这里公布的 NCAP 原理可加快设计用于锌基水性电化学储能系统的开拓性电解质添加剂。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Nano-Micro Letters
Nano-Micro Letters NANOSCIENCE & NANOTECHNOLOGY-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
32.60
自引率
4.90%
发文量
981
审稿时长
1.1 months
期刊介绍: Nano-Micro Letters is a peer-reviewed, international, interdisciplinary, and open-access journal published under the SpringerOpen brand. Nano-Micro Letters focuses on the science, experiments, engineering, technologies, and applications of nano- or microscale structures and systems in various fields such as physics, chemistry, biology, material science, and pharmacy.It also explores the expanding interfaces between these fields. Nano-Micro Letters particularly emphasizes the bottom-up approach in the length scale from nano to micro. This approach is crucial for achieving industrial applications in nanotechnology, as it involves the assembly, modification, and control of nanostructures on a microscale.
期刊最新文献
Wafer-Scale Ag2S-Based Memristive Crossbar Arrays with Ultra-Low Switching-Energies Reaching Biological Synapses Bioinspired Ultrasensitive Flexible Strain Sensors for Real-Time Wireless Detection of Liquid Leakage Direct Photolithography of WOx Nanoparticles for High-Resolution Non-Emissive Displays Exploration of Gas-Dependent Self-Adaptive Reconstruction Behavior of Cu2O for Electrochemical CO2 Conversion to Multi-Carbon Products Flexible Strain Sensors with Ultra-High Sensitivity and Wide Range Enabled by Crack-Modulated Electrical Pathways
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1