s-scheme3D/3D Bi0/BiOBr/P Doped g-C3 N4 with Oxygen Vacancies (Ov) for Photodegradation of Pharmaceuticals: In-situ H2O2 Production and Plasmon Induced Stability

Abstract

Complications accompanying photocatalyst stability and recombination of exciton charges in pollutants degradation has been addressed through the construction of heterojunctions, especially S-scheme heterojunction with strong and distinctive redox centres. Herein, an S-scheme BiOBr (BOR) and g-C₃N₄PO₄ (CNPO) catalyst (BORCNPO) with oxygen vacancy (Ov) was synthesized for levofloxacin (LVX) and oxytetracycline (OTC) photodegradation under visible light. The 3D/3D BORCNPO catalyst possessed C−O−Br bridging bonds for efficient charge transfer during the fabrication of S-scheme heterojunction. In-situ H₂O₂ formation affirmed by potassium titanium (IV) oxalate spectrophotometric method improved the mineralization ability of BORCNPO7.5 catalyst. Bi⁰ surface plasmon resonance (SPR) enhanced formation and involvement of ⋅O₂⁻ and the stability of the catalyst which increased reaction rate with increasing cycling experiments. XPS and radical trapping experiments supported the S-scheme charge transfer mechanism formation with high degradation rate of LVX which was 3 times higher than OTC degradation rate. Mineralization of pollutants and their intermediates were demonstrated with florescence excitation and emission matrix (FEEM) and quadruple time of flight high performance liquid chromatography (QTOF-HPLC). This work advances development of highly stable and efficient catalysts for photodegradation of pollutants through the formation of S-scheme heterostructure.