Ecological mortars produced from sustainable hydrated lime obtained from biomass ash

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Abstract

Sustainable hydrated lime is produced from biomass ash rich in calcium carbonate, with properties similar to industrial hydrated lime. However, there is a lack of current and relevant research on sustainability related to the use of alternative limestone, derived from waste such as biomass ash. In this sense, the present research aims to study the behavior of cementitious coating mortars with partial and total replacement of industrial hydrated lime by sustainable hydrated lime, through microstructural, macrostructural, physical and chemical tests. Microstructural analyses performed by SEM demonstrated the presence of cement hydration products (CSH and ettringite) in all mortars evaluated. Chemical analyses through XRF and XRD showed similarity in chemical composition and crystallographic phases between the mortar with industrial hydrated lime and the ecological mortars. The FTIR showed chemical bonds characteristic of cement mortars in all ecological mortars, ratified by TG/DTG, which shows the decomposition of products such as CSH, ettringite, portlandite and calcite in all ecological mortars. Through the results found, the viability of replacing sustainable hydrated lime with industrial hydrated lime in the preparation of ecological mortars stands out, at the optimum percentage of 50 %, with possible total replacement (100 %) without significant losses in resistance.

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用从生物质灰烬中提取的可持续熟石灰生产生态灰泥
可持续的熟石灰是用富含碳酸钙的生物质灰生产的,其性质与工业熟石灰相似。然而,目前还缺乏与使用生物质灰烬等废弃物制成的替代石灰石相关的可持续性研究。因此,本研究旨在通过微观结构、宏观结构、物理和化学测试,研究用可持续熟石灰部分或全部替代工业熟石灰的水泥基涂料砂浆的行为。通过扫描电子显微镜进行的微观结构分析表明,在所有评估的砂浆中都存在水泥水化产物(CSH 和乙长石)。通过 XRF 和 XRD 进行的化学分析显示,使用工业熟石灰的砂浆与生态砂浆的化学成分和结晶相类似。傅立叶变换红外光谱(FTIR)显示了所有生态砂浆中水泥砂浆特有的化学键,TG/DTG 证实了这一点,它显示了所有生态砂浆中 CSH、乙曲矿、波长石和方解石等产物的分解。结果表明,在制备生态砂浆时,用工业熟石灰替代可持续熟石灰是可行的,最佳比例为 50%,也有可能完全替代(100%),而不会造成明显的抗性损失。
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