Andy Shun-Hoi Cheung , Ming-Yi Leung , Tony Ho-Ching Fung , Vivian Wing-Wah Yam
{"title":"Photoactivable malachite green-based alkynylplatinum(ii) 2,6-bis(N-alkylbenzimidazol-2-yl)pyridine complexes†","authors":"Andy Shun-Hoi Cheung , Ming-Yi Leung , Tony Ho-Ching Fung , Vivian Wing-Wah Yam","doi":"10.1039/d4cc03558e","DOIUrl":null,"url":null,"abstract":"<div><div>Photo-responsive malachite green moieties have been incorporated into an alkynylplatinum(<span>ii</span>) bzimpy system. The photo-caged complexes in acetonitrile solutions exhibit self-assembly properties modulable by photo-removal of the cyano protecting group. Distinct aggregate morphologies, which are facilitated by the non-covalent metal–metal and π–π stacking interactions, have been observed before and after photo-irradiation.</div></div>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"60 77","pages":"Pages 10676-10679"},"PeriodicalIF":4.2000,"publicationDate":"2024-08-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1359734524018093","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Photo-responsive malachite green moieties have been incorporated into an alkynylplatinum(ii) bzimpy system. The photo-caged complexes in acetonitrile solutions exhibit self-assembly properties modulable by photo-removal of the cyano protecting group. Distinct aggregate morphologies, which are facilitated by the non-covalent metal–metal and π–π stacking interactions, have been observed before and after photo-irradiation.
期刊介绍:
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