Phosphine ligand-dependent nickel-catalyzed regiodivergent isomerization of alkenes

IF 11.5 Q1 CHEMISTRY, PHYSICAL Chem Catalysis Pub Date : 2024-08-15 DOI:10.1016/j.checat.2024.101089
Jin-Ping Wang, Peng Wang
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引用次数: 0

Abstract

Regioselective isomerization of alkenes enables efficient alkene preparation with 100% atom economy. In this issue of Chem Catalysis, Chen, Zhao, Wang, and co-workers present a Ni-catalyzed method for producing kinetic and thermodynamic products with high yields and excellent regioselectivity, highlighting the phosphine ligand’s role in controlling regioselectivity.

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膦配体依赖性镍催化的烯烃变异异构化反应
烯的区域选择性异构化可实现原子经济性 100% 的高效烯制备。在本期的《化学催化》(Chem Catalysis)杂志上,Chen、Zhao、Wang 及合作者介绍了一种在镍催化下生产动力学和热力学产物的方法,该方法具有高产率和优异的区域选择性,突出了膦配体在控制区域选择性方面的作用。
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来源期刊
CiteScore
10.50
自引率
6.40%
发文量
0
期刊介绍: Chem Catalysis is a monthly journal that publishes innovative research on fundamental and applied catalysis, providing a platform for researchers across chemistry, chemical engineering, and related fields. It serves as a premier resource for scientists and engineers in academia and industry, covering heterogeneous, homogeneous, and biocatalysis. Emphasizing transformative methods and technologies, the journal aims to advance understanding, introduce novel catalysts, and connect fundamental insights to real-world applications for societal benefit.
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