Aghogho A. Olomukoro, Ruichao Xie, Fabiola X. Fernandez Paucar, Charlotte DeRosa, Neil D. Danielson, Emanuela Gionfriddo
{"title":"Characterization of a mixed mode fluorocarbon/weak anion exchange sorbent for the separation of perfluoroalkyl substances","authors":"Aghogho A. Olomukoro, Ruichao Xie, Fabiola X. Fernandez Paucar, Charlotte DeRosa, Neil D. Danielson, Emanuela Gionfriddo","doi":"10.1002/jssc.202400413","DOIUrl":null,"url":null,"abstract":"<p>The ubiquitous presence and persistence of per- and polyfluoroalkyl substances (PFAS) in the environment have raised concerns in the scientific community. Current research efforts are prioritizing effective PFAS remediation through novel sorbents with orthogonal interaction mechanisms. Recognized sorption mechanisms between PFAS and sorbents include hydrophobic, electrostatic, and fluorine-fluorine interaction. The interplay of these mechanisms contributes significantly to improved sorption capacity and selectivity in PFAS separations. In this study, a primary/secondary amine-functionalized polystyrene-divinylbenzene (Sepra-WAX) polymer was modified to create a fluorinated WAX resin (Sepra-WAX-KelF-PEI). The synthesis intermediate (Sepra-WAX-KelF) was also tested to assess the improvement of the final product (Sepra-WAX-KelF-PEI). The adsorption capacity of Sepra-WAX, Sepra-WAX-KelF, and Sepra-WAX-KelF-PEI, and their interactions with PFAS were evaluated. The effect of pH, ionic strength, and organic solvents on PFAS sorption in aqueous solution was also investigated. The sorbents showed varied adsorption capacities for perfluorooctanoic acid, perfluoropentanoic acid, perfluoro-n-decanoic acid, and hexafluoropropylene oxide dimer acid, with the average extraction capacity of the four analytes being Sepra-WAX-KelF-PEI (523 mg/g) > Sepra-WAX (353 mg/g) > Sepra-WAX-KelF (220 mg/g). Sepra-WAX-KelF-PEI provided the highest adsorption capacity for all analytes tested, proving that the combination of electrostatic and hydrophobic/fluorophilic interactions is crucial for the effective preconcentration of PFAS and its future applications for PFAS remediation from aqueous solutions.</p>","PeriodicalId":17098,"journal":{"name":"Journal of separation science","volume":null,"pages":null},"PeriodicalIF":2.8000,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of separation science","FirstCategoryId":"5","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/jssc.202400413","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The ubiquitous presence and persistence of per- and polyfluoroalkyl substances (PFAS) in the environment have raised concerns in the scientific community. Current research efforts are prioritizing effective PFAS remediation through novel sorbents with orthogonal interaction mechanisms. Recognized sorption mechanisms between PFAS and sorbents include hydrophobic, electrostatic, and fluorine-fluorine interaction. The interplay of these mechanisms contributes significantly to improved sorption capacity and selectivity in PFAS separations. In this study, a primary/secondary amine-functionalized polystyrene-divinylbenzene (Sepra-WAX) polymer was modified to create a fluorinated WAX resin (Sepra-WAX-KelF-PEI). The synthesis intermediate (Sepra-WAX-KelF) was also tested to assess the improvement of the final product (Sepra-WAX-KelF-PEI). The adsorption capacity of Sepra-WAX, Sepra-WAX-KelF, and Sepra-WAX-KelF-PEI, and their interactions with PFAS were evaluated. The effect of pH, ionic strength, and organic solvents on PFAS sorption in aqueous solution was also investigated. The sorbents showed varied adsorption capacities for perfluorooctanoic acid, perfluoropentanoic acid, perfluoro-n-decanoic acid, and hexafluoropropylene oxide dimer acid, with the average extraction capacity of the four analytes being Sepra-WAX-KelF-PEI (523 mg/g) > Sepra-WAX (353 mg/g) > Sepra-WAX-KelF (220 mg/g). Sepra-WAX-KelF-PEI provided the highest adsorption capacity for all analytes tested, proving that the combination of electrostatic and hydrophobic/fluorophilic interactions is crucial for the effective preconcentration of PFAS and its future applications for PFAS remediation from aqueous solutions.
期刊介绍:
The Journal of Separation Science (JSS) is the most comprehensive source in separation science, since it covers all areas of chromatographic and electrophoretic separation methods in theory and practice, both in the analytical and in the preparative mode, solid phase extraction, sample preparation, and related techniques. Manuscripts on methodological or instrumental developments, including detection aspects, in particular mass spectrometry, as well as on innovative applications will also be published. Manuscripts on hyphenation, automation, and miniaturization are particularly welcome. Pre- and post-separation facets of a total analysis may be covered as well as the underlying logic of the development or application of a method.