WS2 with Controllable Layer Number Grown Directly on W Film.

IF 4.4 3区 材料科学 Q2 CHEMISTRY, MULTIDISCIPLINARY Nanomaterials Pub Date : 2024-08-16 DOI:10.3390/nano14161356
Yuxin Zhang, Shiyi Feng, Jin Guo, Rong Tao, Zhixuan Liu, Xiangyi He, Guoxia Wang, Yue Wang
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Abstract

As a layered material with single/multi-atom thickness, two-dimensional transition metal sulfide WS2 has attracted extensive attention in the field of science for its excellent physical, chemical, optical, and electrical properties. The photoelectric properties of WS2 are even more promising than graphene. However, there are many existing preparation methods for WS2, but few reports on its direct growth on tungsten films. Therefore, this paper studies its preparation method and proposes an innovative two-dimensional material preparation method to grow large-sized WS2 with higher quality on metal film. In this experiment, it was found that the reaction temperature could regulate the growth direction of WS2. When the temperature was below 950 °C, the film showed horizontal growth, while when the temperature was above 1000 °C, the film showed vertical growth. At the same time, through Raman and band gap measurements, it is found that the different thicknesses of precursor film will lead to a difference in the number of layers of WS2. The number of layers of WS2 can be controlled by adjusting the thickness of the precursor.

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直接在 W 薄膜上生长的层数可控的 WS2。
作为一种具有单原子/多原子厚度的层状材料,二维过渡金属硫化物 WS2 因其优异的物理、化学、光学和电学特性而受到科学界的广泛关注。WS2 的光电特性甚至比石墨烯更有前途。然而,目前已有许多制备 WS2 的方法,但有关其在钨薄膜上直接生长的报道却很少。因此,本文对其制备方法进行了研究,并提出了一种创新的二维材料制备方法,以在金属膜上生长出更高质量的大尺寸 WS2。实验发现,反应温度可以调节 WS2 的生长方向。当温度低于 950 ℃ 时,薄膜呈水平生长,而当温度高于 1000 ℃ 时,薄膜呈垂直生长。同时,通过拉曼和带隙测量发现,不同厚度的前驱体薄膜会导致 WS2 层数的不同。可以通过调整前驱体的厚度来控制 WS2 的层数。
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来源期刊
Nanomaterials
Nanomaterials NANOSCIENCE & NANOTECHNOLOGY-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
8.50
自引率
9.40%
发文量
3841
审稿时长
14.22 days
期刊介绍: Nanomaterials (ISSN 2076-4991) is an international and interdisciplinary scholarly open access journal. It publishes reviews, regular research papers, communications, and short notes that are relevant to any field of study that involves nanomaterials, with respect to their science and application. Thus, theoretical and experimental articles will be accepted, along with articles that deal with the synthesis and use of nanomaterials. Articles that synthesize information from multiple fields, and which place discoveries within a broader context, will be preferred. There is no restriction on the length of the papers. Our aim is to encourage scientists to publish their experimental and theoretical research in as much detail as possible. Full experimental or methodical details, or both, must be provided for research articles. Computed data or files regarding the full details of the experimental procedure, if unable to be published in a normal way, can be deposited as supplementary material. Nanomaterials is dedicated to a high scientific standard. All manuscripts undergo a rigorous reviewing process and decisions are based on the recommendations of independent reviewers.
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