Gas–liquid mass-transfer characteristics during dissolution and evolution in quasi-static and dynamic processes

Abstract

This study aims to understand the comprehensive behavior of the gas–liquid flow and dissolution–evolution mass transfer. A quasi-static closed-tank experiment was designed to measure the static mass-transfer coefficients of the dissolution and evolution processes using the diffusion equation. After a detailed uncertainty analysis, a dynamic ventilated-pipe experiment with different-sized orifice plates was designed to illustrate the relationship between the hydrodynamic parameters, physical structure, and gas–liquid mass-transfer characteristics. The results showed that, as the static pressure and liquid-level height increase, both the dissolution and evolution coefficients exhibit increasing trends. However, when the physical condition reaches the initial state after pressurization and depressurization, the gas absorbed by the solution cannot completely evolve from the solution; that is, the dissolution rate is always greater than or equal to the evolution rate. For the equal-diameter pipe, as the gas flow rate increases, the concentration increment decreases slightly after reaching the peak, owing to the reduction in mass-transfer time caused by the increase in liquid flow rate. In particular, the maximal dissolved concentration, an increment of 210.9 %, occurred in the double large-orifice plate with the ventilated condition, far exceeding the maximum value in the quasi-static process. Moreover, the concentration under the layout of two small-orifice plates decreases slightly, and the larger gas content enables the solution to have more gas nuclei, making it easier to induce the gas evolution. The current study provides guidance for the gas–liquid-mixture transportation and improvement of the dissolved efficiency.