Preparation of Poly(allylamine Hydrochloride) Grafted Porous Boron Nitride Fibers for Efficient Cr(VI) Adsorption from Aqueous Solution.

Abstract

Cr(VI) pollution poses great harm to the cyclic utilization of groundwater and surface water resources. Efficient adsorbent materials have great potential to change this situation and assist in the restoration of ecosystems. This work chooses porous boron nitride fibers (pBN) with stable physical and chemical properties as the matrix, 3-aminopropyltriethoxysilane (APTES) as the coupling agent, and uses a one-step crosslinking method to graft poly(allylamine hydrochloride) (PAH) onto pBN, forming pBN-AS@PAH with fascinating Cr(VI) adsorption capacity. PAH is uniformly covered and modified on the surface of pBN, and the composite with high specific surface area (383.33 m²/g), large pore volume (0.37 cm³/g), and abundant amino groups. Its equilibrium adsorption capacity for Cr(VI) can reach up to 123.32 mg/g, and the adsorption behavior follows the quasi second-order kinetic model and Langmuir model, indicating the chemical adsorption process of monolayer. The adsorption style belongs to a spontaneous exothermic process and has the optimal adsorption effect at a pH of ~2. Additionally, after cycling for 5 times, the decrease rate of adsorption capacity is less than 10 %, showing an excellent reusability.