Realizations of Su-Schrieffer-Heeger (SSH) edge states in two-dimensional hydrocarbon systems

Abstract

The Su-Schrieffer-Heeger (SSH) model of one-dimensional (1D) diatomic and four-atom chains, exhibit a topological phase transition characterized by the Zak phase. However, a challenge arises from the inherent difficulty of maintaining strong structural stability in real 1D nanostructures. Here, we show how to realize periodic 1D chains, reminiscent of the SSH model, in a two-dimensional (2D) system. These chains form a quasi-1D chain topological insulator (CTI) where the interchain coupling can be neglected. Based on first-principles calculations, we proposed that such CTIs can be realized in dumbbell (DB) C₄₀H₁₄ and DB C₄₀H₁₂ monolayers. The monolayers are CTIs, with a type of weak topological state, and the topological phase transition can be achieved by unit cell transformation or the application of 2D strain. Furthermore, increasing the number of DB C₁₀H₄ rings can enlarge the distance between the chains, corresponding to line defects within the monolayer, providing a possible strategy for experimental synthesis.