Dr. Na Xu, Dr. Wanmin Chen, Dr. Jun Miao, Dr. Yousong Ding, Prof. Zhiping Zheng
{"title":"Innenrücktitelbild: Unraveling the Intertwining Factors Underlying the Assembly of High-Nuclearity Heterometallic Clusters (Angew. Chem. 37/2024)","authors":"Dr. Na Xu, Dr. Wanmin Chen, Dr. Jun Miao, Dr. Yousong Ding, Prof. Zhiping Zheng","doi":"10.1002/ange.202414386","DOIUrl":null,"url":null,"abstract":"<p><b>Two structurally intricate</b> heterometallic clusters with cores featuring multiple Platonic and Archimedean polyhedra were synthesized by ligand-controlled co-hydrolysis of Ni<sup>2+</sup> and Dy<sup>3+</sup> ions, as reported by Zhiping Zheng et al. in their Research Article (e202409109). Adjusting the amount of hydrolysis-promoting base and the reaction temperature and duration afforded selectively the kinetic and thermodynamic species, respectively with a Dy<sub>112</sub>Ni<sub>76</sub> and a Dy<sub>52</sub>Ni<sub>44</sub> core.\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure>\n </p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202414386","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Angewandte Chemie","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ange.202414386","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
Two structurally intricate heterometallic clusters with cores featuring multiple Platonic and Archimedean polyhedra were synthesized by ligand-controlled co-hydrolysis of Ni2+ and Dy3+ ions, as reported by Zhiping Zheng et al. in their Research Article (e202409109). Adjusting the amount of hydrolysis-promoting base and the reaction temperature and duration afforded selectively the kinetic and thermodynamic species, respectively with a Dy112Ni76 and a Dy52Ni44 core.