Innenrücktitelbild: Unraveling the Intertwining Factors Underlying the Assembly of High-Nuclearity Heterometallic Clusters (Angew. Chem. 37/2024)

Dr. Na Xu, Dr. Wanmin Chen, Dr. Jun Miao, Dr. Yousong Ding, Prof. Zhiping Zheng
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Abstract

Two structurally intricate heterometallic clusters with cores featuring multiple Platonic and Archimedean polyhedra were synthesized by ligand-controlled co-hydrolysis of Ni2+ and Dy3+ ions, as reported by Zhiping Zheng et al. in their Research Article (e202409109). Adjusting the amount of hydrolysis-promoting base and the reaction temperature and duration afforded selectively the kinetic and thermodynamic species, respectively with a Dy112Ni76 and a Dy52Ni44 core.

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Innenrücktitelbild:揭示高核度异金属团簇组装背后的交织因素(Angew.)
郑志平等人在其研究文章(e202409109)中报道了通过配体控制Ni2+和Dy3+离子的共水解作用合成了两种结构复杂的异金属簇,其核具有多个柏拉图和阿基米德多面体。通过调节水解促进碱的用量、反应温度和持续时间,可以选择性地得到分别以 Dy112Ni76 和 Dy52Ni44 为核心的动力学和热力学物种。
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Angewandte Chemie
Angewandte Chemie 化学科学, 有机化学, 有机合成
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