{"title":"Laser additive manufacturing of a carbon-supersaturated β-Ti alloy for biomaterial application","authors":"","doi":"10.1016/j.addlet.2024.100233","DOIUrl":null,"url":null,"abstract":"<div><p>Developing high-performance β-Ti alloys is a persistent and long-term demand for the advancement of next-generation biomaterials. In this study, a strategy of leveraging the unique characteristics of laser powder bed fusion (L-PBF) technique and nanocarbon materials was proposed to design a novel carbon-supersaturated β-Ti alloy. Ultrathin graphene oxide (GO) sheets were closely covering onto spherical Ti-15Mo-5Zr-3Al (Ti1553) powders, enhancing laser absorptivity while maintaining good flowability. Consequently, the GO-added Ti1553 builds tended to be denser than the initial ones, indicating an improved additive manufacturability. During <span>L</span>-PBF, GO sheets were completely dissolved into the Ti1553 matrix, generating fully carbon-supersaturated β-Ti structures with a reduced grain size. Thanks to the exceptional strengthening effects of high-concentration solid-solution carbon (∼0.05 wt%), the GO/Ti1553 builds achieved a high ultimate tensile strength of 1166 MPa. Moreover, as revealed by the immunofluorescence staining experiments, the GO/Ti1553 builds demonstrated a retained cytocompatibility. This study provides new insight into composition and processing design of high-performance Ti components for biomedical applications.</p></div>","PeriodicalId":72068,"journal":{"name":"Additive manufacturing letters","volume":null,"pages":null},"PeriodicalIF":4.2000,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772369024000410/pdfft?md5=f91ca5affc8917d8cbab1f3b90e6769a&pid=1-s2.0-S2772369024000410-main.pdf","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Additive manufacturing letters","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2772369024000410","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, MANUFACTURING","Score":null,"Total":0}
引用次数: 0
Abstract
Developing high-performance β-Ti alloys is a persistent and long-term demand for the advancement of next-generation biomaterials. In this study, a strategy of leveraging the unique characteristics of laser powder bed fusion (L-PBF) technique and nanocarbon materials was proposed to design a novel carbon-supersaturated β-Ti alloy. Ultrathin graphene oxide (GO) sheets were closely covering onto spherical Ti-15Mo-5Zr-3Al (Ti1553) powders, enhancing laser absorptivity while maintaining good flowability. Consequently, the GO-added Ti1553 builds tended to be denser than the initial ones, indicating an improved additive manufacturability. During L-PBF, GO sheets were completely dissolved into the Ti1553 matrix, generating fully carbon-supersaturated β-Ti structures with a reduced grain size. Thanks to the exceptional strengthening effects of high-concentration solid-solution carbon (∼0.05 wt%), the GO/Ti1553 builds achieved a high ultimate tensile strength of 1166 MPa. Moreover, as revealed by the immunofluorescence staining experiments, the GO/Ti1553 builds demonstrated a retained cytocompatibility. This study provides new insight into composition and processing design of high-performance Ti components for biomedical applications.