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Agentic additive manufacturing alloy evaluation 代理增材制造合金评价
IF 4.7 Q2 ENGINEERING, MANUFACTURING Pub Date : 2026-04-01 Epub Date: 2026-01-09 DOI: 10.1016/j.addlet.2026.100355
Peter Pak , Achuth Chandrasekhar , Amir Barati Farimani
Agentic systems enable the intelligent use of research tooling, augmenting a researcher’s ability to investigate and propose novel solutions to existing problems. Within Additive Manufacturing (AM), alloy selection and evaluation remains a complex challenge, often requiring expertise in the various domains of materials science, thermodynamic simulations, and experimental analysis. Large Language Model (LLM) enabled agents can facilitate this endeavor by utilizing their extensive knowledge base to dispatch tool calls via Model Context Protocol (MCP) to perform actions such as thermophysical property diagram calculations and lack of fusion process map generation. In addition, the multi-agent system can effectively reason through complex user prompts and provide analysis on the lack of fusion process window of common alloys such as SS316L and IN718 along with proposed composition variants of known alloys. These agents can dynamically adjust their task trajectory to the outcomes of tool call results, effectively enabling autonomous decision-making in practical environments. This work aims to showcase the benefits of adopting a LLM enabled multi-agent system to automate and accelerate the task of evaluating proposed additive manufacturing alloys, both novel and known.
代理系统能够智能地使用研究工具,增强研究人员对现有问题进行调查和提出新解决方案的能力。在增材制造(AM)中,合金的选择和评估仍然是一个复杂的挑战,通常需要材料科学、热力学模拟和实验分析等各个领域的专业知识。支持大型语言模型(LLM)的代理可以通过利用其广泛的知识库通过模型上下文协议(MCP)调度工具调用来执行诸如热物理性质图计算和缺乏融合过程图生成等操作,从而促进这一努力。此外,多智能体系统可以通过复杂的用户提示进行有效推理,分析SS316L、IN718等常用合金缺乏熔合过程窗口的原因,并提出已知合金的成分变体。这些智能体可以根据工具调用结果动态调整其任务轨迹,有效地实现在实际环境中的自主决策。这项工作旨在展示采用LLM支持的多智能体系统的好处,以自动化和加速评估拟议的增材制造合金的任务,无论是新颖的还是已知的。
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引用次数: 0
Approximation of absorptivity conditions for Inconel 625 from in situ radiation thermometry measurements in electron beam powder bed fusion 电子束粉末床熔合中原位辐射测温对铬镍铁合金625吸收条件的近似
IF 4.7 Q2 ENGINEERING, MANUFACTURING Pub Date : 2026-04-01 Epub Date: 2026-01-06 DOI: 10.1016/j.addlet.2026.100354
Shadman Tahsin Nabil , Alfonso Fernandez , Francisco Medina , Ralph Felice , James P. Carney , César A. Terrazas-Nájera
Highly dynamic conditions experienced during metals processing using powder bed fusion (PBF) additive manufacturing (AM) arise from the interaction of multiple process variables. Chiefly amongst them is the energy source-material interaction, which results in abrupt, temporally changing thermal conditions at the melt-pool. The absorption of the energy from the source by the powder bed is complicated complex because this interaction is highly dynamic and occluded by process emissions including the plasma plume and spatter. Typical approaches for measuring absorption conditions have relied on intricate ex situ setups requiring extensive sample preparation. This work involved approximating the absorptivity for a nickel-base material from in situ observations made using a multi-wavelength (MW) pyrometry sensor, while processing using electron-beam based powder bed fusion (PBF-EB/M). The prediction step involved fitting the spectral data captured by the MW sensor to then extrapolate values to shorter wavelengths. The approximation was done for wavelengths that are relevant for the PBF-LB/M process, where absorptivity of the laser energy is paramount. The results obtained provide a window into the behavior of this material as it transitions from powder to molten state, showing that the absorptivity substantially decreases (∼60% reduction) as the powder material changes phase induced by incipient melting. While this work focuses on a single material, the approach presented can help characterize the absorptivity of other materials employed in PBF. This work helps support both experimental and modeling efforts that are helpful to increase our understanding and practice of fusion-based AM processes, and other manufacturing techniques.
粉末床熔融增材制造(AM)金属加工过程中的高动态条件是由多个过程变量的相互作用引起的。其中最主要的是能量源与物质的相互作用,这种相互作用导致了熔池中突然的、暂时性的热条件变化。粉末床对源能量的吸收是复杂的,因为这种相互作用是高度动态的,并且被包括等离子体羽流和飞溅在内的过程发射遮挡。测量吸收条件的典型方法依赖于复杂的非原位装置,需要大量的样品制备。这项工作包括使用多波长(MW)热测量传感器在现场观察中近似镍基材料的吸收率,同时使用基于电子束的粉末床熔合(PBF-EB/M)进行处理。预测步骤包括拟合由MW传感器捕获的光谱数据,然后将值外推到更短的波长。近似是对与PBF-LB/M工艺相关的波长进行的,其中激光能量的吸收率是最重要的。所获得的结果为该材料从粉末状态转变为熔融状态的行为提供了一个窗口,表明随着粉末材料由初熔引起的相变,吸收率大幅降低(降低约60%)。虽然这项工作侧重于单一材料,但所提出的方法可以帮助表征PBF中使用的其他材料的吸收率。这项工作有助于支持实验和建模工作,有助于增加我们对基于融合的增材制造工艺和其他制造技术的理解和实践。
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引用次数: 0
Adaptive-binder-aggregate mixing (ABAM): Concept for extrusion-based multi-material 3D concrete printing 自适应粘结剂-骨料混合(ABAM):基于挤压的多材料3D混凝土打印概念
IF 4.7 Q2 ENGINEERING, MANUFACTURING Pub Date : 2026-04-01 Epub Date: 2025-12-31 DOI: 10.1016/j.addlet.2025.100353
Christian Maximilian Hechtl , Maximilian Dahlenburg , Freek Bos , Thomas Kränkel , Christoph Gehlen
3D concrete printing (3DCP) enables layerwise fabrication with digital control, offering geometric freedom and material efficiency. However, conventional pump-based 3DCP is constrained by conflicting material requirements, namely sufficient workability for pumping and extrusion versus sufficient resistance to flow and early-age structural build-up for buildability after deposition. This paper introduces Adaptive-Binder-Aggregate Mixing (ABAM), a process concept that avoids long-distance pumping of an aggregate-rich printable cementitious composite (PCC), which can be critical for porous lightweight aggregates and can limit feasible aggregate size and volume fraction. Instead, a pumpable cementitious compound (CC) without aggregates is prepared in the stationary environment and conveyed to the end-effector, where aggregates are stored and incorporated near the nozzle to form the PCC shortly before deposition. The process enables functional material gradation by switching aggregate type during printing, allowing spatial property tailoring within a monolithic element. A prototype implementation is presented together with an initial feasibility demonstration.
3D混凝土打印(3DCP)通过数字控制实现分层制造,提供几何自由度和材料效率。然而,传统的基于泵的3DCP受到相互冲突的材料要求的限制,即足够的泵送和挤压可加工性与足够的流动阻力和沉积后可建造性的早期结构堆积。本文介绍了自适应粘结剂-骨料混合(ABAM),这是一种工艺概念,可以避免长距离泵送富含骨料的可打印胶凝复合材料(PCC),这对于多孔轻质骨料来说是至关重要的,并且可以限制可行的骨料尺寸和体积分数。相反,在固定环境中制备不含骨料的可泵送胶凝化合物(CC),并将其输送到末端执行器,在末端执行器中,骨料被储存并结合在喷嘴附近,在沉积之前形成PCC。该工艺通过在打印过程中切换聚合类型来实现功能性材料分级,从而在整体元素中实现空间属性剪裁。给出了一个原型实现,并进行了初步的可行性论证。
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引用次数: 0
Electroslag additive manufacturing: A pathway for high throughput near net shape production 电渣增材制造:高通量近净形状生产的途径
IF 4.7 Q2 ENGINEERING, MANUFACTURING Pub Date : 2026-04-01 Epub Date: 2025-12-02 DOI: 10.1016/j.addlet.2025.100343
Adam G. Stevens , Vanshika Singh , Rangasayee Kannan , David Hebble , Sarah Graham , Paritosh Mhatre , Kevin Zinn , Christopher Masuo , William Carter , Jesse Heineman , Andres Marquez Rossy , Alexandra B. Shanafield , Charles Savage , Alex Roschli , Brian Hicks , Peeyush Nandwana , S.S. Babu , Brian K. Post
Electroslag Additive Manufacturing (ESAM), a new high-throughput additive manufacturing (AM) method that combines Electroslag Strip Cladding (ESC) and wire arc AM (WAAM) is introduced. This combination enables the high deposition rate of ESC (more than 20 kg/h with a 60 mm strip electrode) to benefit from the precise geometric control of WAAM. As a precursor to ESAM, the ESC process is investigated in an AM context independently by evaluating both direct and staggered bead-stacking strategies and analyzing the microstructural and mechanical properties of each. This is followed by an ESAM demonstration producing an annular geometry by pairing ESC with gas tungsten arc welding (GTAW), wherein GTAW is utilized to construct annular walls that are subsequently infilled via ESC. The microstructure and mechanical properties of ESC-only AM are compared with that of the ESAM method and it is shown that printed integral retaining walls do not impact the resulting mechanical properties of ESAM. Furthermore, results indicate that ESAM-produced Alloy 625 parts exhibit tensile properties on par with cast counterparts, supporting the method’s scalability to components exceeding one metric ton, and possibly making ESAM a viable future manufacturing approach for competitive production of large-scale components currently manufactured by casting and forging.
介绍了一种结合电渣带包覆(ESC)和电弧增材制造(WAAM)的新型高通量增材制造方法——电渣增材制造(ESAM)。这种组合使ESC的高沉积速率(60mm条形电极超过20kg /h)受益于WAAM的精确几何控制。作为ESAM的先驱,ESC过程在AM背景下进行了独立的研究,通过评估直接和交错堆积策略,并分析每种策略的微观结构和力学性能。随后是ESAM演示,通过将ESC与气体钨极电弧焊(GTAW)配对,产生环形几何形状,其中GTAW用于构建环形壁,随后通过ESC填充。将ESAM与ESAM方法制备的AM的微观结构和力学性能进行了比较,结果表明,印刷整体挡土墙不会影响制备的ESAM的力学性能。此外,结果表明,ESAM生产的625合金零件具有与铸造同等的拉伸性能,支持该方法可扩展到超过1吨的部件,并可能使ESAM成为未来可行的制造方法,用于目前通过铸造和锻造制造的大型部件的竞争性生产。
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引用次数: 0
A Buckingham-Pi dimensionless analysis for melt pool stability and defect prediction in additive manufacturing 增材制造中熔池稳定性和缺陷预测的Buckingham-Pi无量纲分析
IF 4.7 Q2 ENGINEERING, MANUFACTURING Pub Date : 2026-04-01 Epub Date: 2026-02-14 DOI: 10.1016/j.addlet.2026.100366
Mahdi Alishavandi, Rahmi Ünal, Metin U. Salamci
Melt pool instabilities limit the reliability of additive manufacturing. Here, we demonstrate that a minimal Buckingham-π framework, supplemented by a normalized enthalpy (NE) metric, consolidates process outcomes across heat source settings (power, speed, spot) and material properties. IN738LC was processed on an EOS M290; single-track and bulk responses, melt pool geometric features, part relative density (ρ), and areal roughness parameters Sa and Sz, were quantified and subsequently mapped onto compact NE-dimensionless number spaces after the normalized-enthalpy metric had been calibrated using an effective absorptivity inferred from the measured melt pool depth. The recoil number cleanly delineates modes: Recoil2 (conductionstable keyhole) maintains ρ99% with low Sa, whereas Recoil4–5 marks an unstable keyhole with spatter and porosity. Within this map, favorable transport balances are Re100, We<1, small Ca and not-too-small Oh, and Fo>0.1; external convection remains negligible (Nu1). Rather than VED, we advocate working directly in Π-space (NE,Recoil,Re,We,Ca,Oh,Fo,Nu)—to define, compare, and transfer qualifiable process windows across machines and alloys.
熔池的不稳定性限制了增材制造的可靠性。在这里,我们证明了一个最小的Buckingham-π框架,辅以标准化的焓(NE)度量,整合了热源设置(功率、速度、光斑)和材料性能的过程结果。IN738LC在EOS M290上处理;在使用从测量的熔池深度推断出的有效吸收率校准归一化焓度量后,对单轨和总体响应、熔池几何特征、部分相对密度(ρ∗)和面粗糙度参数Sa和Sz进行量化,并随后映射到紧凑的ne -无维数空间。反冲数清晰地描述了模式:在低Sa条件下,反冲系数> 2(传导→稳定锁孔)维持ρ∗≥99%,而反冲系数> 4-5则标志着具有飞溅和孔隙的不稳定锁孔。在这个地图中,有利的运输平衡是Re > 100, We<1,小Ca和不太小的Oh, Fo>0.1;外部对流仍然可以忽略不计(Nu≪1)。我们提倡直接使用Π-space (NE,Recoil,Re, we,Ca,Oh,Fo,Nu)来定义,比较和传递机器和合金的合格工艺窗口,而不是VED。
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引用次数: 0
Cold spray additively manufactured pure iron for magnetic applications 冷喷涂增材制造的纯铁用于磁性应用
IF 4.7 Q2 ENGINEERING, MANUFACTURING Pub Date : 2026-04-01 Epub Date: 2026-02-02 DOI: 10.1016/j.addlet.2026.100363
Abhinav Anand , Ondřej Kovářík , Pavel Ctibor , Zahra Arabgol , Levke Wiehler , Frank Gärtner , Thomas Klassen , Jan Cizek
Pure iron powder combines excellent plastic deformability under a high-velocity impact with high magnetizability and permeability, making it an economical candidate for cold spray additive manufacturing (CSAM) and repairs in magnetic applications. This work explores the fracture mechanics and electromagnetic (EM) properties of CSAM pure iron deposited using cheaper nitrogen as the process gas at temperatures of 900 °C and 1000 °C, achieving relative densities of 97.3 % and 98.0 %, respectively. The deposits exhibited an ultimate tensile strength greater than 250 MPa and elongation to fracture of less than 0.3 %, a behavior consistent with the characteristic results of as-sprayed CSAM deposits. The fatigue crack growth rate analyses showed the propagation being faster than in wrought iron through different mechanisms: trans-particle crack propagation near the threshold stress intensity factor, and inter-particle decohesion at higher loads. The EM testing indicated that CSAM pure iron saturated at a lower induction and had lower permeability than wrought low-carbon steel, while its coercivity and hysteresis losses were higher, and electrical resistivity was similar. Despite the lower mechanical and magnetic performance, CSAM pure iron or similarly deformable ferritic alloys can meet the requirements for low-field, low-frequency, or direct-current applications, and provide a route for direct near-net-shape additive manufacturing or in-situ repair of magnetic components without scraping existing parts.
纯铁粉在高速冲击下具有优异的塑性变形性能,具有高磁化率和磁导率,使其成为冷喷涂增材制造(CSAM)和磁性应用中修复的经济候选材料。在900°C和1000°C的温度下,采用便宜的氮气作为工艺气体,研究了CSAM纯铁的断裂力学和电磁(EM)性能,相对密度分别为97.3%和98.0%。该沉积体的抗拉强度大于250 MPa,断裂伸长率小于0.3%,与喷射态CSAM沉积体的特征相一致。疲劳裂纹扩展速率分析表明,裂纹扩展速度比熟铁更快,其扩展机制不同:在阈值应力强度因子附近的跨颗粒裂纹扩展,以及在高载荷下的颗粒间脱黏。电磁测试表明,CSAM纯铁在较低的感应强度下饱和,磁导率低于变形低碳钢,但其矫顽力和磁滞损失较高,电阻率相近。尽管机械和磁性能较低,但CSAM纯铁或类似可变形铁素体合金可以满足低场、低频或直流应用的要求,并为直接近净形状增材制造或磁性部件的原位修复提供了一条途径,而不会刮伤现有部件。
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引用次数: 0
Multi-nozzle molten metal droplet jetting 多喷嘴熔融金属液滴喷射
IF 4.7 Q2 ENGINEERING, MANUFACTURING Pub Date : 2026-04-01 Epub Date: 2026-01-17 DOI: 10.1016/j.addlet.2026.100357
Irtaza Razvi , Kareem Tawil , Chris Chunbin , David Trauernicht , Daniel Cormier , Zipeng Guo , Denis Cormier
Molten metal droplet jetting (MMJ) is an emerging metal additive manufacturing (AM) technology that can use low-cost wire, rod, or even ingot feedstock material. This paper describes the architecture and preliminary implementation of what is believed to be among the first demonstrations of MMJ with a multi-nozzle array that is akin to inkjet printing using molten metal as the ink. A multi-nozzle printhead with a communal reservoir and three piezoelectric actuator pistons is presented. The drive waveforms for each nozzle are independently addressable, thus enabling precise control over drop placement for raster printing of arbitrary layer shapes. A jetting strategy is described in which variable track spacing is achieved by altering the yaw angle of the printhead. This yaw angle method allows printed row pitches that are less than or equal to the nozzle pitch. The printhead and build strategy are applied to demonstrate feasibility of the method with single and multi-layer test sample geometries. The influence of these initial results on future multi-nozzle systems is discussed.
熔融金属液滴喷射(MMJ)是一种新兴的金属增材制造(AM)技术,可以使用低成本的线材、棒材甚至铸锭原料。本文描述了被认为是MMJ的第一个多喷嘴阵列演示的架构和初步实现,该阵列类似于使用熔融金属作为墨水的喷墨打印。提出了一种带有公共储液器和三个压电致动活塞的多喷嘴打印头。每个喷嘴的驱动波形都是独立可寻址的,因此可以精确控制任意层形状的光栅打印的滴位置。描述了一种通过改变打印头的偏航角来实现可变轨迹间距的喷射策略。这种偏航角方法允许打印的排距小于或等于喷嘴距。通过打印头和构建策略,验证了该方法在单层和多层测试样品几何形状下的可行性。讨论了这些初步结果对未来多喷嘴系统的影响。
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引用次数: 0
Metal droplet breakup and rapid solidification behavior under multi-stage-controlled atomization process: NiTi alloys 3D printing special powder preparation 多级控制雾化过程下金属液滴破碎和快速凝固行为:NiTi合金3D打印专用粉末制备
IF 4.7 Q2 ENGINEERING, MANUFACTURING Pub Date : 2026-04-01 Epub Date: 2026-02-02 DOI: 10.1016/j.addlet.2026.100365
Jingshan Liu , Ge Zhou , Wenjingzi Wang , Haoyu Zhang , Bingqian Jin , Lijia Chen , Xin Liu , Qi Shi , Ximin Zang
In view of the problem of coordinated control of powder particle size distribution and surface quality during the preparation process of NiTi shape memory alloy 3D printing special metal powder EIGA method, a novel multi-stage-controlled gas atomization method is presented in this study to address the coordinated control of powder particle size distribution and surface quality. The process experiment, comprehensive powder performance test, and characterization of composition and microstructure were carried out, along with the construction of a theoretical model and mechanism research of metal droplet breakup and rapid solidification under multi-field coupling control. The results show that for the breaking behavior of metal droplets, the multi-stage-controlled gas atomization method can maximize the surface energy of metal droplets, which is beneficial to droplet breaking. For the spheroidization and solidification behavior, under the multi-stage-controlled gas atomization pressure, by adjusting the heating power and the feed rate of the bar, the mismatch between the solidification and spheroidization behavior of the droplets can be effectively improved (Ф = tspheroidization / tsolidification ≈ 1). The sphericity and surface quality of the powder are improved. The NiTi alloy powder prepared by this method retained its main elements. The maximum increments of O and N elements are 310 ppm and 70 ppm, and D90 is 50.3 μm. The powder sphericity is good, significantly reducing the number of hollow and satellite powders. This method plays a vital role in improving the application of NiTi alloy powder in 3D printing.
针对NiTi形状记忆合金3D打印专用金属粉末EIGA方法制备过程中粉末粒度分布与表面质量的协调控制问题,提出了一种新型多级控制气体雾化方法,解决粉末粒度分布与表面质量的协调控制问题。进行了工艺试验、粉末综合性能测试、成分和显微组织表征,建立了多场耦合控制下金属液滴破碎和快速凝固的理论模型和机理研究。结果表明,对于金属液滴的破碎行为,多级控制的气体雾化方法可以最大限度地提高金属液滴的表面能,有利于液滴的破碎。对于球化和凝固行为,在多级控制的雾化压力下,通过调节加热功率和棒料进料速度,可以有效改善液滴的凝固和球化行为不匹配的问题(Ф = tspheroidization / t凝固≈1)。提高了粉末的球形度和表面质量。用该方法制备的NiTi合金粉末保留了主要元素。O和N元素的最大增量分别为310 ppm和70 ppm, D90为50.3 μm。粉末球形度好,大大减少了空心粉和卫星粉的数量。该方法对提高NiTi合金粉末在3D打印中的应用具有至关重要的作用。
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引用次数: 0
Enabling powder bed fusion (PBF) processing of polyether imide (PEI) through mixed-phase solvent processing 通过混相溶剂处理实现聚醚亚胺(PEI)的粉末床熔融(PBF)加工
IF 4.7 Q2 ENGINEERING, MANUFACTURING Pub Date : 2026-04-01 Epub Date: 2026-02-20 DOI: 10.1016/j.addlet.2026.100369
C. Garrett Campbell , Camden Chatham , Samantha J. (Lindholm) Knight , E. Cade Willis , Andrew P. Rhodes
Polymeric material options for powder bed fusion (PBF) additive manufacturing (AM) techniques are typically limited to semicrystalline thermoplastics with large differences between their melting and recrystallization temperatures. Amorphous thermoplastics like polyetherimides (PEIs) are desired in certain applications but cannot be effectively processed by PBF due to their lack of crystallinity. Herein, we present a new solvent processing method which induces crystallinity in a particular grade of PEI, Ultem CRS5011, thus enabling its processing by these techniques. This new solvent treatment approach improves on others reported in the literature which either use carcinogenic solvents or yield solvent-soaked powders that are difficult to process in the 1–5 kg range suitable for bench-top units. In an initial scoping study, we identify acetophenone as a suitable non-hazardous solvent for this process which we then scale to the ∼kilogram scale. Finally, we demonstrate processability of this feedstock by PBF-LB/P using a bed temperature (Tbed) well above the Tg of this feedstock.
粉末床熔融(PBF)增材制造(AM)技术的聚合物材料选择通常仅限于半结晶热塑性塑料,其熔融温度和再结晶温度之间存在很大差异。非晶态热塑性塑料如聚醚酰亚胺(PEIs)在某些应用中是需要的,但由于其缺乏结晶度,PBF不能有效地加工。在此,我们提出了一种新的溶剂加工方法,该方法可以诱导特定等级的PEI, Ultem CRS5011的结晶度,从而使其能够通过这些技术进行加工。这种新的溶剂处理方法改进了文献中报道的其他方法,这些方法要么使用致癌溶剂,要么产生难以在1-5千克范围内加工的溶剂浸泡粉末,适用于台式装置。在最初的范围研究中,我们确定苯乙酮是适用于该工艺的无害溶剂,然后我们将其扩展到~千克规模。最后,我们使用远高于该原料Tg的床温(Tbed),通过PBF-LB/P证明了该原料的可加工性。
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引用次数: 0
Effect of TiN nanoparticle on shape memory properties of additively manufactured ferrous high entropy shape memory alloy TiN纳米颗粒对增材制造亚铁高熵形状记忆合金形状记忆性能的影响
IF 4.7 Q2 ENGINEERING, MANUFACTURING Pub Date : 2026-04-01 Epub Date: 2026-01-07 DOI: 10.1016/j.addlet.2026.100356
Guoyuan Qiu , Yaning Tang , Jianjun Lin , Jeremy Heng Rao , Xing Gong , Changyong Liu , Zhangwei Chen , Chao Dong , Zhiyuan Liu
Emerging 4D printing is an innovative additive manufacturing (AM) technique that incorporates an extra dimension of time into AM. 4D printed objects can change their shapes or properties in response to external stimuli. However, the intrinsic microstructural anisotropy also affects the shape memory performance of AM printed shape memory alloys (SMAs). This work investigated the effect of TiN nanoparticle addition on the mechanical and shape-memory properties of a high entropy shape memory alloy (HESMA) Fe50Mn20Co10Cr10Si10 (at.%) fabricated by laser powder bed fusion (LPBF). Results show that the TiN addition enhances the yield strength (YS) of the AM HESMA at the expense of ductility. Meanwhile, the as-built shape memory performance is reduced, with the maximum bending recovery strain of the vertical sample decreasing from 6.3 % to 4.7 %. Moreover, it is shown that introducing TiN nanoparticles can significantly alleviate the 4D-printing anisotropy. The YS anisotropy ratio is reduced from 40.0 % to 20.5 %, and the shape memory anisotropy ratio decreases from 56.3 % to 14.9 %. The underlying reason is attributed to a columnar-to-equiaxed microstructure transition induced by the TiN addition, which results in similar amount of grain boundaries during deformation in different directions. To restore the shape memory ability, the TiN/HESMA is subjected to further heat treatment. The maximum recovery strain is improved greatly and approaching that of HESMA matrix, and the shape memory anisotropy ratio further decreases to 3.4 %. The underlying mechanism of the heat treatment is revealed. The synergy of TiN addition and heat treatment provides a novel approach to balance strength enhancement and functional anisotropy of 4D printing
新兴的4D打印是一种创新的增材制造(AM)技术,它将额外的时间维度纳入AM。4D打印的物体可以根据外界刺激改变其形状或特性。然而,固有的微观结构各向异性也会影响增材制造形状记忆合金的形状记忆性能。本文研究了添加TiN纳米颗粒对激光粉末床熔合法制备的高熵形状记忆合金Fe50Mn20Co10Cr10Si10 (at.%)的力学性能和形状记忆性能的影响。结果表明,TiN的加入提高了AM HESMA的屈服强度,但牺牲了延性。同时,材料的形状记忆性能下降,竖向试样的最大弯曲恢复应变从6.3%下降到4.7%。此外,研究表明,引入TiN纳米颗粒可以显著缓解3d打印的各向异性。YS各向异性比从40.0%降低到20.5%,形状记忆各向异性比从56.3%降低到14.9%。其根本原因是由于TiN的加入导致了柱状组织向等轴组织的转变,导致不同方向的变形过程中晶界数量相近。为了恢复形状记忆能力,对TiN/HESMA进行进一步热处理。最大恢复应变显著提高,接近HESMA基体,形状记忆各向异性比进一步降低至3.4%。揭示了热处理的基本机理。添加TiN和热处理的协同作用为平衡4D打印的强度增强和功能各向异性提供了一种新的方法
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引用次数: 0
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Additive manufacturing letters
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