Printable ionic liquid modified cellulose acetate for sustainable chromic and resistive temperature sensing

Abstract

Sustainable technologies and the circular economy paradigms require a reduction of waste, and therefore, research is focusing on the development of sustainable materials and devices capable of being reused, refurbished or recycled.

In the present work, printable ionic liquid (IL)-based polymer composites with thermochromic properties have been developed through a more sustainable approach to mitigate the negative impact of advanced functional materials and processes. For this purpose, composite films based on a natural polymer, cellulose acetate (CA), and different contents of the thermochromic IL, bis(1-butyl-3-methylimidazolium) tetrachloronickelate ([Bmim]₂[NiCl₄]), have been processed by a solvent casting method for the development of sustainable temperature sensors. The composites are transparent at room temperature, but when exposed to a temperature of 50 °C, the colour changes to blue. Incorporating the thermochromic IL led to the appearance of pores in the material's structure, which increased with increasing IL concentration. Additionally, the Young Modulus decreases with increasing IL concentration, reaching a value of 840 ± 158 MPa) for the sample with 40 % wt. Contrarily, the electrical conductivity strongly increases with the highest DC electrical conductivity, with a maximum conductivity of 1.1 × 10–5 ± 1.5 × 10–6 S.cm-1 obtained for the sample with 40 % wt. of [Bmim]₂[NiCl₄].

As a proof of concept, the potential applicability of the developed natural-based nanoparticle-free materials was demonstrated with a CA/40[Bmim]₂[NiCl₄] sample by the development of printable thermochromic temperature sensors for thermotherapy applications in the temperature range from 33 °C to 50 °C.