{"title":"Ni-Fe2O3@SiO2-Pr-DBU: A novel efficient magnetically retrievable catalyst for one-pot synthesis of dihydropyrano [3,2-c] chromene","authors":"Lalit Bhosale , Rutikesh Gurav , Akshay Gurav , Sandeep Sankpal , Shankar Hangirgekar","doi":"10.1016/j.jorganchem.2024.123341","DOIUrl":null,"url":null,"abstract":"<div><p>In the present work, Ni-Fe<sub>2</sub>O<sub>3</sub>@SiO<sub>2</sub>-Pr-DBU was synthesized as a novel magnetically separable nano-catalyst and characterized by various techniques like Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), Scanning electron microscopy (SEM), Vibrating-sample magnetometry (VSM), Transmission electron microscopy (TEM) and Elemental analysis by energy dispersive X-ray (EDX). The catalytic efficiency of NiFe<sub>2</sub>O<sub>3</sub>@SiO<sub>2</sub>-Pr-DBU was explored in the synthesis of dihydropyrano[3,2-c] chromenes through a one-pot multicomponent reaction of 4-hydroxycoumarin, malononitrile, and aryl aldehydes in aqueous solution at ambient temperature condition. An external magnet easily removed the nano-sized magnetic core catalyst from the synthesized reaction mixture. It was recycled for five successive runs while maintaining its potential and adhering to our green synthesis approach. We used dihydropyrano chromene, a highly biologically active commercial compound, to prepare some novel derivatives.</p></div>","PeriodicalId":374,"journal":{"name":"Journal of Organometallic Chemistry","volume":"1021 ","pages":"Article 123341"},"PeriodicalIF":2.1000,"publicationDate":"2024-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Organometallic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0022328X2400336X","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
In the present work, Ni-Fe2O3@SiO2-Pr-DBU was synthesized as a novel magnetically separable nano-catalyst and characterized by various techniques like Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), Scanning electron microscopy (SEM), Vibrating-sample magnetometry (VSM), Transmission electron microscopy (TEM) and Elemental analysis by energy dispersive X-ray (EDX). The catalytic efficiency of NiFe2O3@SiO2-Pr-DBU was explored in the synthesis of dihydropyrano[3,2-c] chromenes through a one-pot multicomponent reaction of 4-hydroxycoumarin, malononitrile, and aryl aldehydes in aqueous solution at ambient temperature condition. An external magnet easily removed the nano-sized magnetic core catalyst from the synthesized reaction mixture. It was recycled for five successive runs while maintaining its potential and adhering to our green synthesis approach. We used dihydropyrano chromene, a highly biologically active commercial compound, to prepare some novel derivatives.
期刊介绍:
The Journal of Organometallic Chemistry targets original papers dealing with theoretical aspects, structural chemistry, synthesis, physical and chemical properties (including reaction mechanisms), and practical applications of organometallic compounds.
Organometallic compounds are defined as compounds that contain metal - carbon bonds. The term metal includes all alkali and alkaline earth metals, all transition metals and the lanthanides and actinides in the Periodic Table. Metalloids including the elements in Group 13 and the heavier members of the Groups 14 - 16 are also included. The term chemistry includes syntheses, characterizations and reaction chemistry of all such compounds. Research reports based on use of organometallic complexes in bioorganometallic chemistry, medicine, material sciences, homogeneous catalysis and energy conversion are also welcome.
The scope of the journal has been enlarged to encompass important research on organometallic complexes in bioorganometallic chemistry and material sciences, and of heavier main group elements in organometallic chemistry. The journal also publishes review articles, short communications and notes.