Observation of tapered multicore fibers based on Nb2CTx for humidity sensing: Experiment and DFT simulation investigations

Abstract

Recent advancements in the area of human healthcare monitoring and medical diagnosis have sparked a revived interest in humidity sensors. Nb₂CT_x, characterized by its multilayered structure, large specific surface area, and plentiful hydrophilic groups, actively absorbs a sufficient quantity of water molecules. In this work, the sensing capability and mechanism of water molecules are investigated under different proportions of functional group distribution on the surface of Nb₂CT_x MXene employing plane-wave based density functional theory calculations, and the provided models can offer guiding principles for the experimental preparation of the highly sensitive humidity sensor based on Nb₂CT_x. To verify the effectiveness of the model, Nb₂CT_x material is coated on a Tapered Three-Core Fiber (TTCF), and the high evanescent field characteristics of the sensor are utilized to further improve its performance. As the relative humidity (RH) increased from 35 % to 75 %, the transmitted spectra exhibited a redshift with a sensitivity of 22pm/% RH. Within the relative humidity range of 75 % to 95 %, the Nb₂CT_x coating heightened water molecule absorption, resulting in a more pronounced redshift in the transmitted spectra. This phase manifests a maximum humidity sensitivity of 299pm/% RH. Noteworthy advantages of this sensor include its uncomplicated structure, cost-effectiveness, and robust stability, rendering it highly suitable a wide variety of potential applications in fields such as biology, chemical and health processing.