{"title":"Keplerate polyoxometalate compounds: a multifunctional nano-platform for advanced materials","authors":"Ken Wang, Tsukasa Iwano and Sayaka Uchida","doi":"10.1039/D4DT02114B","DOIUrl":null,"url":null,"abstract":"<p >Polyoxometalates (POMs) are robust, discrete, and structurally well-defined metal–oxide cluster anions that have stimulated research in broad fields of science. Keplerates, as porous giant POMs, serve as a multifunctional nano-platform exhibiting fascinating chemical properties stemming from the porous molecular structure, substantial interior space, delocalization of d-electrons over the large molecular surface, <em>etc</em>. Consequently, Keplerates have attracted significant attention from scientists in the fields of chemistry, physics, biology, and materials sciences. This work reviews recent research progress on Keplerates as nanocontainers, catalysts, and battery materials. Furthermore, current challenges and potential future research directions are discussed, providing a reference for the development and effective application of Keplerates and Keplerate-based materials.</p>","PeriodicalId":71,"journal":{"name":"Dalton Transactions","volume":" 41","pages":" 16797-16806"},"PeriodicalIF":3.3000,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Dalton Transactions","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/dt/d4dt02114b","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
Polyoxometalates (POMs) are robust, discrete, and structurally well-defined metal–oxide cluster anions that have stimulated research in broad fields of science. Keplerates, as porous giant POMs, serve as a multifunctional nano-platform exhibiting fascinating chemical properties stemming from the porous molecular structure, substantial interior space, delocalization of d-electrons over the large molecular surface, etc. Consequently, Keplerates have attracted significant attention from scientists in the fields of chemistry, physics, biology, and materials sciences. This work reviews recent research progress on Keplerates as nanocontainers, catalysts, and battery materials. Furthermore, current challenges and potential future research directions are discussed, providing a reference for the development and effective application of Keplerates and Keplerate-based materials.
聚氧化金属酸盐（POMs）是一种坚固、离散、结构明确的金属氧化物簇阴离子，激发了广泛科学领域的研究。Keplerates 作为多孔的巨型 POM，作为一种多功能纳米平台，因其多孔的分子结构、巨大的内部空间、大分子表面上的 d 电子析出等特性而表现出迷人的化学性质。因此，开普勒石引起了化学、物理学、生物学和材料科学领域科学家的极大关注。本研究综述了开普勒酸盐作为纳米容器、催化剂或电池材料的最新研究进展。此外，还讨论了当前面临的挑战和未来潜在的研究方向，为开普勒盐和开普勒盐基材料的开发和有效应用提供参考。
期刊介绍：
Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.
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