A comprehensive review on designing nanocomposite adsorbents for efficient removal of 4-nitrophenol from water

IF 5.45 Q1 Physics and Astronomy Nano-Structures & Nano-Objects Pub Date : 2024-09-11 DOI:10.1016/j.nanoso.2024.101326
Noureddine El Messaoudi , Youssef Miyah , Mohammed Benjelloun , Jordana Georgin , Dison S.P. Franco , Zeynep Mine Şenol , Zeynep Ciğeroğlu , Maryam El Hajam , Salah Knani , Phuong Nguyen-Tri
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Abstract

Water is the basic entity required for the survival of any life form on earth. However, in the present scenario, due to its contamination with various types of contaminants, there is a global crisis of water. One of the major organic pollutants described to be present in most industrial-modeled water is 4-nitrophenol. Due to its persistence and high potential for bioaccumulation, it is considered a high-priority environmental and health concern. Numerous nanomaterials are considered to have huge potential in the treatment of contaminated water due to their unique high surface area as well as some beneficial properties that support work even in low concentrations. In the last few years, much attention has been paid by scientists to different applications of nanocomposites for water purification. This review represents a comprehensive approach to how to enhance nanocomposite-mediated adsorption for effective 4-NP removal from modeled water. It involves high adsorption capacity, with adsorbents calcium and aluminum layered double hydroxide-loaded magnetic nanocomposite and magnetite nanoparticles, with capacities as high as 598 mg g-1 and 636 mg g-1, respectively. Such advanced materials may improve the hydrophilicity and mechanical properties of the material. The processes could be endothermic and exothermic in nature. pH also plays a role in performance, where, in most studies, conditions above 6 corroborate the removal of 4-NP. Textural properties and functional groups present on the surface of the adsorbent also determine whether the process is physical or chemical. Further studies should be focused on large-scale decontamination of the contaminant, entrenching the use of low-cost and environmentally friendly adsorbents that are more environmentally acceptable in real applications. This would not enable researchers to follow up with new strategies for the remediation of water that is contaminated with 4-NP on the basis of making a model for engineering nanocomposites for the remediation of contaminants.

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关于设计纳米复合吸附剂以高效去除水中 4-硝基苯酚的综述
水是地球上任何生命形式赖以生存的基本物质。然而,在目前的情况下,由于受到各种污染物的污染,全球都面临着水危机。据描述,在大多数工业用水中存在的主要有机污染物之一是 4-硝基苯酚。由于其持久性和高生物累积潜力,它被认为是一个高度优先的环境和健康问题。许多纳米材料因其独特的高表面积和一些有益的特性,即使在低浓度下也能发挥作用,因此被认为在处理受污染的水方面具有巨大的潜力。在过去几年中,科学家们非常关注纳米复合材料在水净化方面的不同应用。本综述全面介绍了如何增强纳米复合材料介导的吸附作用,从而有效去除模型水中的 4-NP。它涉及高吸附容量,吸附剂钙铝层状双氢氧化物负载磁性纳米复合材料和磁铁矿纳米颗粒的吸附容量分别高达 598 mg g-1 和 636 mg g-1。这种先进的材料可以改善材料的亲水性和机械性能。pH 值对性能也有影响,在大多数研究中,pH 值高于 6 的条件下可以去除 4-NP。吸附剂表面的纹理特性和官能团也决定了该过程是物理过程还是化学过程。进一步研究的重点应放在大规模污染物净化上,从而确保在实际应用中使用更环保的低成本环保型吸附剂。这样一来,研究人员就无法在建立污染物修复工程纳米复合材料模型的基础上,跟进受 4-NP 污染的水的修复新策略。
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来源期刊
Nano-Structures & Nano-Objects
Nano-Structures & Nano-Objects Physics and Astronomy-Condensed Matter Physics
CiteScore
9.20
自引率
0.00%
发文量
60
审稿时长
22 days
期刊介绍: Nano-Structures & Nano-Objects is a new journal devoted to all aspects of the synthesis and the properties of this new flourishing domain. The journal is devoted to novel architectures at the nano-level with an emphasis on new synthesis and characterization methods. The journal is focused on the objects rather than on their applications. However, the research for new applications of original nano-structures & nano-objects in various fields such as nano-electronics, energy conversion, catalysis, drug delivery and nano-medicine is also welcome. The scope of Nano-Structures & Nano-Objects involves: -Metal and alloy nanoparticles with complex nanostructures such as shape control, core-shell and dumbells -Oxide nanoparticles and nanostructures, with complex oxide/metal, oxide/surface and oxide /organic interfaces -Inorganic semi-conducting nanoparticles (quantum dots) with an emphasis on new phases, structures, shapes and complexity -Nanostructures involving molecular inorganic species such as nanoparticles of coordination compounds, molecular magnets, spin transition nanoparticles etc. or organic nano-objects, in particular for molecular electronics -Nanostructured materials such as nano-MOFs and nano-zeolites -Hetero-junctions between molecules and nano-objects, between different nano-objects & nanostructures or between nano-objects & nanostructures and surfaces -Methods of characterization specific of the nano size or adapted for the nano size such as X-ray and neutron scattering, light scattering, NMR, Raman, Plasmonics, near field microscopies, various TEM and SEM techniques, magnetic studies, etc .
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