Enhancing the coloration of polypropylene surfaces through low-frequency plasma modification with disperse dyes

IF 3.2 3区 材料科学 Q2 ENGINEERING, CHEMICAL International Journal of Adhesion and Adhesives Pub Date : 2024-09-10 DOI:10.1016/j.ijadhadh.2024.103837
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Abstract

This study focuses on the effective coloring of nonwoven polypropylene surfaces, achieved through the application of oxygen and nitrogen plasma treatments in a vacuum environment using cold plasma. Various plasma durations were employed to introduce experimental diversity into the samples. Following surface modification, dispersal dyeing based on benzenesulphonamide was performed. To evaluate the impact of surface modification, comprehensive characterization tests, including SEM, FTIR-ATR, XRD, and XPS, were conducted. Performance effects were scrutinized through color spectrum values (CIE L*, a*, b*, and K/S values), tearing strengths and contact angle measurements. Furthermore, fastness tests for washing (color change and staining) and for rubbing (dry and wet) were carried out to examine the effect of surface modification on dyed polypropylene nonwoven fabrics. According to the test results, a notable increase in K/S values was observed after plasma treatments. The impact of nitrogen and oxygen plasma treatment on polypropylene surfaces was comprehensively evaluated, considering performance properties across all characterization processes.

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通过低频等离子体改性分散染料提高聚丙烯表面的着色效果
本研究的重点是通过在真空环境中使用冷等离子体进行氧和氮等离子体处理,实现对聚丙烯无纺布表面的有效着色。实验中采用了不同的等离子体持续时间,以在样品中引入实验多样性。表面改性后,进行了基于苯磺酰胺的分散染料染色。为了评估表面改性的影响,进行了全面的表征测试,包括 SEM、FTIR-ATR、XRD 和 XPS。通过色谱值(CIE L*、a*、b* 和 K/S 值)、撕裂强度和接触角测量,对性能效果进行了仔细研究。此外,还进行了水洗牢度(变色和染色)和摩擦牢度(干摩擦和湿摩擦)测试,以检验表面改性对染色聚丙烯无纺布的影响。测试结果表明,经过等离子处理后,K/S 值明显增加。考虑到所有表征过程的性能特性,对氮和氧等离子处理对聚丙烯表面的影响进行了全面评估。
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来源期刊
International Journal of Adhesion and Adhesives
International Journal of Adhesion and Adhesives 工程技术-材料科学:综合
CiteScore
6.90
自引率
8.80%
发文量
200
审稿时长
8.3 months
期刊介绍: The International Journal of Adhesion and Adhesives draws together the many aspects of the science and technology of adhesive materials, from fundamental research and development work to industrial applications. Subject areas covered include: interfacial interactions, surface chemistry, methods of testing, accumulation of test data on physical and mechanical properties, environmental effects, new adhesive materials, sealants, design of bonded joints, and manufacturing technology.
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