Sr-Yb Co-doping of BaCe0.4Zr0.6O3 Proton-Conducting Electrolyte for Solid Oxide Fuel Cells

IF 2.2 4区 工程技术 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Journal of Electronic Materials Pub Date : 2024-09-10 DOI:10.1007/s11664-024-11400-6
Jihai Cheng, Lingling Xu, Hao Liang
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Abstract

Ba0.9Sr0.1Ce0.4Zr0.6−xYbxO3−δ(x = 0.05, 0.1, 0.15, 0.2) proton-conducting electrolyte powders were synthesized by the nitrate combustion method. The effects of co-doping of Sr and Yb on the phase composition and electrochemical performance were studied. X-ray diffraction (XRD) results indicate that Sr and Yb were successfully doped into the lattice of BaCe0.4Zr0.6O3, forming a single perovskite phase. The AC impedance technique was used to investigate the total conductivity of the materials under air and water vapor atmospheres at 400–800°C. The results show that BSCZY20 demonstrated the highest electrical conductivity of 0.033 S cm−1 at 800°C in water vapor. This suggests that the co-doping strategy can effectively enhance the conductivity of BaCe0.4Zr0.6O3 proton-conducting material, which provides valuable insight for the development of high-performance proton-conducting solid oxide fuel cells.

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用于固体氧化物燃料电池的 BaCe0.4Zr0.6O3 质子传导电解质的 Sr-Yb Co 掺杂
采用硝酸盐燃烧法合成了 Ba0.9Sr0.1Ce0.4Zr0.6-xYbxO3-δ(x = 0.05、0.1、0.15、0.2)质子传导电解质粉末。研究了 Sr 和 Yb 共掺杂对相组成和电化学性能的影响。X 射线衍射 (XRD) 结果表明,Sr 和 Yb 成功地掺杂到了 BaCe0.4Zr0.6O3 的晶格中,形成了单一的包晶相。交流阻抗技术用于研究材料在 400-800°C 的空气和水蒸气环境下的总电导率。结果表明,BSCZY20 在 800°C 水蒸气环境下的导电率最高,达到 0.033 S cm-1。这表明共掺杂策略能有效提高 BaCe0.4Zr0.6O3 质子导电材料的电导率,为开发高性能质子传导型固体氧化物燃料电池提供了宝贵的启示。
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来源期刊
Journal of Electronic Materials
Journal of Electronic Materials 工程技术-材料科学:综合
CiteScore
4.10
自引率
4.80%
发文量
693
审稿时长
3.8 months
期刊介绍: The Journal of Electronic Materials (JEM) reports monthly on the science and technology of electronic materials, while examining new applications for semiconductors, magnetic alloys, dielectrics, nanoscale materials, and photonic materials. The journal welcomes articles on methods for preparing and evaluating the chemical, physical, electronic, and optical properties of these materials. Specific areas of interest are materials for state-of-the-art transistors, nanotechnology, electronic packaging, detectors, emitters, metallization, superconductivity, and energy applications. Review papers on current topics enable individuals in the field of electronics to keep abreast of activities in areas peripheral to their own. JEM also selects papers from conferences such as the Electronic Materials Conference, the U.S. Workshop on the Physics and Chemistry of II-VI Materials, and the International Conference on Thermoelectrics. It benefits both specialists and non-specialists in the electronic materials field. A journal of The Minerals, Metals & Materials Society.
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