Digital Colorimetric Analysis of Aqueous and Aqueous–Organic Systems Using Polyvinyl Alcohol–Magnetite Hydrophilic Composite Films

IF 1 4区 化学 Q4 CHEMISTRY, ANALYTICAL Journal of Analytical Chemistry Pub Date : 2024-09-03 DOI:10.1134/S1061934824700576
I. S. Shchemelev, T. V. Zinov’ev, A. V. Ivanov, N. B. Ferapontov
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Abstract

The application of composite films consisting of crosslinked polyvinyl alcohol and magnetite as sensitive elements in the determination of the composition of aqueous solutions by digital colorimetry is described. A novel approach to fabricating composite materials of the composition hydrophilic polymer–magnetite is proposed; it involves the precipitation of Fe3O4 particles in ammonia vapors. The sensor films produced by this method were employed for determining the volume fraction of alcohol in products characterized by high alcohol content. The limit of detection for ethanol was determined at 63 vol %, while for isopropanol, it 24 vol %. The efficacy of the proposed sensor materials was assessed through in an analysis of liquid hand sanitizers.

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使用聚乙烯醇-磁铁矿亲水复合膜对水性和水有机体系进行数字比色分析
摘要 介绍了由交联聚乙烯醇和磁铁矿组成的复合薄膜作为敏感元件在数字比色法测定水溶液成分中的应用。文中提出了一种制造亲水性聚合物-磁铁矿复合材料的新方法,即在氨蒸汽中沉淀 Fe3O4 颗粒。用这种方法制作的传感器薄膜可用于测定酒精含量高的产品中酒精的体积分数。乙醇的检测极限为 63 Vol %,异丙醇为 24 Vol %。通过对液体洗手液的分析,对所提出的传感器材料的功效进行了评估。
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来源期刊
Journal of Analytical Chemistry
Journal of Analytical Chemistry 化学-分析化学
CiteScore
2.10
自引率
9.10%
发文量
146
审稿时长
13 months
期刊介绍: The Journal of Analytical Chemistry is an international peer reviewed journal that covers theoretical and applied aspects of analytical chemistry; it informs the reader about new achievements in analytical methods, instruments and reagents. Ample space is devoted to problems arising in the analysis of vital media such as water and air. Consideration is given to the detection and determination of metal ions, anions, and various organic substances. The journal welcomes manuscripts from all countries in the English or Russian language.
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