Gas Chromatographic Analysis of the Distribution γ-Hexachlorocyclohexane in Agricultural Crops

IF 1 4区 化学 Q4 CHEMISTRY, ANALYTICAL Journal of Analytical Chemistry Pub Date : 2024-08-24 DOI:10.1134/S1061934824700448
D. E. Musabirov, R. A. Daukaev, D. O. Karimov, V. Y. Guskov
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Abstract

The work is devoted to the study of the distribution of γ-hexachlorocyclohexane in turnips and beets between their bulbs, tops, and skin. The sample preparation procedure recommended by GOST is supplemented by the use of liquid nitrogen for the deeper crushing and destruction of plant cells. It was found that the use of liquid nitrogen, with other experimental parameters being constant, leads to a 2–3-fold increase in the amount of the pesticide being determined. It was found that the distribution of γ-HCCH in plants is uneven: the highest concentration of the pesticide is found in the skin, while the amount of γ-HCCH in the tops was the lowest. It was shown that the pesticide is better accumulated in beet skin than in turnip skin; for the tops the pattern is reversed, and the accumulation of γ-HCCH in the bulbs of these root crops is similar in magnitude. The obtained data can be useful for analytical quality control services of agricultural products.

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农作物中的γ-六氯环己烷分布气相色谱分析
摘要 这项工作致力于研究γ-六氯环己烷在萝卜和甜菜的球茎、顶部和表皮之间的分布情况。在采用 GOST 建议的样品制备程序的同时,还使用液氮对植物细胞进行深度粉碎和破坏。研究发现,在其他实验参数不变的情况下,使用液氮可使测定的农药量增加 2-3 倍。研究发现,γ-HCH 在植物体内的分布是不均匀的:表皮中的农药浓度最高,而顶部的 γ-HCCH 含量最低。研究表明,甜菜表皮中的杀虫剂累积量比芜菁表皮中的要高;而顶部的情况则相反,γ-HCH 在这些根茎作物鳞茎中的累积量相差无几。所获得的数据可用于农产品的分析质量控制服务。
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来源期刊
Journal of Analytical Chemistry
Journal of Analytical Chemistry 化学-分析化学
CiteScore
2.10
自引率
9.10%
发文量
146
审稿时长
13 months
期刊介绍: The Journal of Analytical Chemistry is an international peer reviewed journal that covers theoretical and applied aspects of analytical chemistry; it informs the reader about new achievements in analytical methods, instruments and reagents. Ample space is devoted to problems arising in the analysis of vital media such as water and air. Consideration is given to the detection and determination of metal ions, anions, and various organic substances. The journal welcomes manuscripts from all countries in the English or Russian language.
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