Integrating TiNx to Fe-based amorphous coating by reactive plasma spray for ameliorating multi-scale mechanical behavior and corrosion-abrasion resistance

Abstract

Ocean engineering components are subjected to intense corrosion and abrasion. To address these challenges, the Fe-based amorphous composite coating was engineered for compatibility with these harsh conditions. The Fe-based amorphous composite coating, incorporating TiN_x, demonstrated improved nanomechanical properties, offering enhanced resistance against external forces. The integration of TiN_x acted as a structural backbone, limiting crack propagation within the amorphous matrix. Although the corrosion resistance of this composite coating was slightly reduced, it demonstrated improved durability subjected to hydraulic machinery corrosion abrasion working condition. Notably, under conditions of higher tribological pair speeds and increased sand concentrations, this composite coating exhibited significantly lower weight loss increase and reduced wear rates escalation compared to coatings made entirely from Fe-based amorphous material. Moreover, the composite coating exhibited diminished susceptibility to erosion damage, with reduced size and severity of erosion craters. These underlying mechanisms are thoroughly discussed in the paper.