{"title":"Sustainable Wastewater Treatment with Bi2MoO6/Cellulose Acetate Photocatalytic Membranes","authors":"Velusamy Sasikala, Sakarapani Sarala, Palani Karthik, Prakash Natarajan, Azhagurajan Mukkannan","doi":"10.1002/ppsc.202400137","DOIUrl":null,"url":null,"abstract":"A major challenge for modern society is securing quality water for various uses. Membrane water treatment will be crucial for drinking water, desalination, and wastewater reuse. The development of bismuth molybdate (Bi<jats:sub>2</jats:sub>MoO<jats:sub>6</jats:sub>) nanoparticles has enabled the production of novel Bi<jats:sub>2</jats:sub>MoO<jats:sub>6</jats:sub>‐incorporated cellulose acetate (CA) membrane nanocomposite. The synthesized Bi<jats:sub>2</jats:sub>MoO<jats:sub>6</jats:sub>/CA nanocomposites are thoroughly examined for their structural, morphological, and photocatalytic characteristics using X‐ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), X‐ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM) with energy dispersive X‐ray spectroscopy (EDX) analysis. The photocatalytic properties are determined by evaluating the degradation of Malachite Green (MG) and Rose Bengal (RB) by the nanocomposite membranes under the illumination of a UV light simulator. Notably, the Bi<jats:sub>2</jats:sub>MoO<jats:sub>6</jats:sub>/CA nanocomposite membrane displays exceptional and sustained photocatalytic efficiency (78%) and (84%) in MG and RB dye degradation, respectively. Moreover, the effective loading of the Bi<jats:sub>2</jats:sub>MoO<jats:sub>6</jats:sub> onto the CA membrane enhances electron and hole adsorption while facilitating carrier movement. Furthermore, the stability exhibited by the Bi<jats:sub>2</jats:sub>MoO<jats:sub>6</jats:sub>/CA nanocomposite photocatalysts remains impressive even after multiple cycles, demonstrating their durability. This research introduces a cutting‐edge semiconductor‐based hybrid nanocomposite material that proves highly efficient in the photocatalytic degradation of organic dyes, showcasing promising advancements in environmental remediation strategies.","PeriodicalId":19903,"journal":{"name":"Particle & Particle Systems Characterization","volume":"108 1","pages":""},"PeriodicalIF":2.7000,"publicationDate":"2024-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Particle & Particle Systems Characterization","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1002/ppsc.202400137","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
A major challenge for modern society is securing quality water for various uses. Membrane water treatment will be crucial for drinking water, desalination, and wastewater reuse. The development of bismuth molybdate (Bi2MoO6) nanoparticles has enabled the production of novel Bi2MoO6‐incorporated cellulose acetate (CA) membrane nanocomposite. The synthesized Bi2MoO6/CA nanocomposites are thoroughly examined for their structural, morphological, and photocatalytic characteristics using X‐ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), X‐ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM) with energy dispersive X‐ray spectroscopy (EDX) analysis. The photocatalytic properties are determined by evaluating the degradation of Malachite Green (MG) and Rose Bengal (RB) by the nanocomposite membranes under the illumination of a UV light simulator. Notably, the Bi2MoO6/CA nanocomposite membrane displays exceptional and sustained photocatalytic efficiency (78%) and (84%) in MG and RB dye degradation, respectively. Moreover, the effective loading of the Bi2MoO6 onto the CA membrane enhances electron and hole adsorption while facilitating carrier movement. Furthermore, the stability exhibited by the Bi2MoO6/CA nanocomposite photocatalysts remains impressive even after multiple cycles, demonstrating their durability. This research introduces a cutting‐edge semiconductor‐based hybrid nanocomposite material that proves highly efficient in the photocatalytic degradation of organic dyes, showcasing promising advancements in environmental remediation strategies.
期刊介绍:
Particle & Particle Systems Characterization is an international, peer-reviewed, interdisciplinary journal focusing on all aspects of particle research. The journal joined the Advanced Materials family of journals in 2013. Particle has an impact factor of 4.194 (2018 Journal Impact Factor, Journal Citation Reports (Clarivate Analytics, 2019)).
Topics covered include the synthesis, characterization, and application of particles in a variety of systems and devices.
Particle covers nanotubes, fullerenes, micelles and alloy clusters, organic and inorganic materials, polymers, quantum dots, 2D materials, proteins, and other molecular biological systems.
Particle Systems include those in biomedicine, catalysis, energy-storage materials, environmental science, micro/nano-electromechanical systems, micro/nano-fluidics, molecular electronics, photonics, sensing, and others.
Characterization methods include microscopy, spectroscopy, electrochemical, diffraction, magnetic, and scattering techniques.