The effect of multielectrode galvanic corrosion behavior and area ratio on 6061 aluminum alloy, Q235 stainless steel, and carbon fiber composites

Guangyi Chen, Xiangdong Huai, Guisheng Xu, Wenzhuo Zhang, Xiaoqiang Han, Decheng Wang, Qi Yin, Dan Xie, Yuli Chen
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Abstract

In this work, electrochemical experiments and numerical simulation methods are employed to study the multielectrode galvanic corrosion behavior of 6061‐Q235‐CFRP, and discuss the influence of the cathode and anode area ratio on the multielectrode galvanic corrosion behavior. The results show that in the 6061‐Q235‐CFRP multielectrode corrosion system, 6061 aluminum alloy is the only anode, and Q235 as well as CFRP are both cathodes. In a multielectrode galvanic system of 6061‐Q235‐CFRP, the current density of 6061 is slightly smaller than the sum of the current densities of 6061 in two galvanic systems of 6061‐Q235 as well as 6061‐CFRP. Moreover, the potential of the galvanic system shifts negatively and the current density decreases gradually with the increasing area of 6061, which has a logarithmic relationship with the area of the cathode and anode. While the current density increases with the increasing area of Q235 or CFRP.
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多电极电化学腐蚀行为和面积比对 6061 铝合金、Q235 不锈钢和碳纤维复合材料的影响
本文采用电化学实验和数值模拟方法研究了 6061-Q235-CFRP 的多电极电化学腐蚀行为,并讨论了阴阳极面积比对多电极电化学腐蚀行为的影响。结果表明,在 6061-Q235-CFRP 多电极腐蚀体系中,6061 铝合金是唯一的阳极,Q235 和 CFRP 都是阴极。在 6061-Q235-CFRP 多电极电镀系统中,6061 的电流密度略小于 6061-Q235 和 6061-CFRP 两个电镀系统中 6061 的电流密度之和。此外,随着 6061 面积的增加,电镀系统的电位会发生负移,电流密度也会逐渐降低,这与阴极和阳极的面积呈对数关系。而电流密度则随着 Q235 或 CFRP 面积的增大而增大。
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